Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R Jin - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Tailoring the photoluminescence of atomically precise nanoclusters

X Kang, M Zhu - Chemical Society Reviews, 2019 - pubs.rsc.org
Due to their atomically precise structures and intriguing chemical/physical properties, metal
nanoclusters are an emerging class of modular nanomaterials. Photo-luminescence (PL) is …

Atomically precise clusters of noble metals: emerging link between atoms and nanoparticles

I Chakraborty, T Pradeep - Chemical reviews, 2017 - ACS Publications
Atomically precise pieces of matter of nanometer dimensions composed of noble metals are
new categories of materials with many unusual properties. Over 100 molecules of this kind …

Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities

R Jin, C Zeng, M Zhou, Y Chen - Chemical reviews, 2016 - ACS Publications
Colloidal nanoparticles are being intensely pursued in current nanoscience research.
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …

Electrochemistry of atomically precise metal nanoclusters

K Kwak, D Lee - Accounts of Chemical Research, 2018 - ACS Publications
Thiolate-protected metal nanoparticles containing a few to few hundred metal atoms are
interesting materials exhibiting unique physicochemical properties. They encompass the …

[HTML][HTML] Ligand effect on switching the rate-determining step of water oxidation in atomically precise metal nanoclusters

Z Liu, H Tan, B Li, Z Hu, D Jiang, Q Yao… - Nature …, 2023 - nature.com
The ligand effects of atomically precise metal nanoclusters on electrocatalysis kinetics have
been rarely revealed. Herein, we employ atomically precise Au25 nanoclusters with different …

Au 25 (SR) 18: the captain of the great nanocluster ship

X Kang, H Chong, M Zhu - Nanoscale, 2018 - pubs.rsc.org
Noble metal nanoclusters are in the intermediate state between discrete atoms and
plasmonic nanoparticles and are of significance due to their atomically accurate structures …

Ultrabright luminescence from gold nanoclusters: rigidifying the Au (I)–thiolate shell

K Pyo, VD Thanthirige, K Kwak… - Journal of the …, 2015 - ACS Publications
Luminescent nanomaterials have captured the imagination of scientists for a long time and
offer great promise for applications in organic/inorganic light-emitting displays …

[Ag48(C≡CtBu)20(CrO4)7]: An Atomically Precise Silver Nanocluster Co-protected by Inorganic and Organic Ligands

SS Zhang, F Alkan, HF Su, CM Aikens… - Journal of the …, 2019 - ACS Publications
The elaborate selection of capping ligands is of great importance in the synthesis of
atomically precise metal nanoclusters. Organic thiolates, alkynyls, phosphines, and/or their …

Mechanistic exploration and controlled synthesis of precise thiolate-gold nanoclusters

N Goswami, Q Yao, T Chen, J Xie - Coordination Chemistry Reviews, 2016 - Elsevier
Well-defined thiolate-gold nanoclusters (generally described as Au n (SR) m NCs, where “n”
and “m” are the numbers of gold atoms and thiolate ligands (–SR), respectively), comprise a …