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This review is dedicated to the chemistry of stable and isolable species that bear two lone
pairs at the same C center, ie, geminal dianions, stabilized by main group elements. Three …

Homoleptic tetramethylaluminates Ln (AlMe4) 3 react with KTp t Bu, Me (Tp t Bu, Me= tris (3-t
Bu-5-Me-pyrazolyl) borato) to yield rare-earth-metal methylidene complexes (Tp t Bu, Me) Ln …

Abstract Rare‐earth‐metal (Ln) alkyl and aryl compounds feature highly reactive, thermally
labile [Ln− C] σ‐bonds which result in rapid and violent decomposition in the presence of air …

Complexes containing multiple bonding interactions between lanthanoid elements and main-group
fragments - RSC Advances (RSC Publishing) DOI:10.1039/C3RA23151H Royal Society of …

Abstract Treatment of [K (BIPMMesH)](BIPMMes={C (PPh2NMes) 2} 2−; Mes= C6H2‐2, 4, 6‐
Me3) with [UCl4 (thf) 3](1 equiv) afforded [U (BIPMMesH)(Cl) 3 (thf)](1), which generated [U …

The rare-earth elements (Ln= Sc, Y, La–Lu) are widely used in stoichiometric and catalytic
carbonyl group transformations. Sufficient availability, non-toxicity, high oxophilicity, tunable …

The structure of a nanospheric polyhydrido copper cluster,[Cu20 (H) 11 {S2P (O i Pr) 2} 9],
was determined by single-crystal neutron diffraction. The Cu20 cluster consists of an …

The hitherto unknown homoleptic tetramethylaluminate complex [Sc (AlMe4) 3] could be
obtained by reacting the ate complex [Li3ScMe6 (thf) 1.2] with AlMe3 in the cold. It …

Reaction of [Ce (NR2) 3](R= SiMe3) with LiNO3 in THF, in the presence of 2, 2, 2-cryptand,
results in the formation of the Ce (III)“ate” complex,[Li (2, 2, 2-cryptand)][Ce (κ2-O2NO)(NR2) …