Heavy Alkali Treatment of Cu(In,Ga)Se2 Solar Cells: Surface versus Bulk Effects

S Siebentritt, E Avancini, M Bär… - Advanced Energy …, 2020 - Wiley Online Library
Chalcopyrite solar cells achieve efficiencies above 23%. The latest improvements are due to
post‐deposition treatments (PDT) with heavy alkalis. This study provides a comprehensive …

Surface and Interface Properties in Thin‐Film Solar Cells: Using Soft X‐rays and Electrons to Unravel the Electronic and Chemical Structure

L Weinhardt, D Hauschild, C Heske - Advanced Materials, 2019 - Wiley Online Library
Thin‐film solar cells have great potential to overtake the currently dominant silicon‐based
solar cell technologies in a strongly growing market. Such thin‐film devices consist of a …

Rationalizing Performance Losses of Wide Bandgap Perovskite Solar Cells Evident in Data from the Perovskite Database

K Suchan, TJ Jacobsson, C Rehermann… - Advanced Energy …, 2024 - Wiley Online Library
Metal halide perovskites (MHPs) have become a widely studied class of semiconductors for
various optoelectronic devices. The possibility to tune their bandgap (Eg) over a broad …

Overall Distribution of Rubidium in Highly Efficient Cu(In,Ga)Se2 Solar Cells

P Schöppe, S Schönherr, P Jackson… - … applied materials & …, 2018 - ACS Publications
Thin-film solar cells based on Cu (In, Ga) Se2 (CIGS) absorbers have achieved conversion
efficiencies close to 23%. Such a high performance could be reached by incorporating …

Rb Diffusion and Oxide Removal at the RbF-Treated Ga2O3/Cu(In,Ga)Se2 Interface in Thin-Film Solar Cells

E Pyatenko, D Hauschild, V Mikhnych… - … Applied Materials & …, 2023 - ACS Publications
We report on the chemical structure of Cu (In, Ga) Se2 (CIGSe) thin-film solar cell absorber
surfaces and their interface with a sputter-deposited Ga2O3 buffer. The CIGSe samples …

Revealing the origin of the beneficial effect of cesium in highly efficient Cu (In, Ga) Se2 solar cells

P Schöppe, S Schönherr, M Chugh, H Mirhosseini… - Nano Energy, 2020 - Elsevier
The record conversion efficiency of thin-film solar cells based on Cu (In, Ga) Se 2 (CIGS)
absorbers has exceeded 23%. Such a high performance is currently only attainable by the …

Electronic Structure of the CdS/Cu(In,Ga)Se2 Interface of KF- and RbF-Treated Samples by Kelvin Probe and Photoelectron Yield Spectroscopy

M Rusu, T Kodalle, L Choubrac… - … Applied Materials & …, 2021 - ACS Publications
Ambient-pressure Kelvin probe and photoelectron yield spectroscopy methods were
employed to investigate the impact of the KF and RbF postdeposition treatments (KF-PDT …

Optimal CdS Buffer Thickness to Form High-Quality CdS/Cu(In,Ga)Se2 Junctions in Solar Cells without Plasma Damage and Shunt Paths

KS Cho, J Jang, JH Park, DK Lee, S Song, K Kim… - ACS …, 2020 - ACS Publications
CdS has been known to be one of the best junction partners for Cu (In, Ga) Se2 (CIGS) in
CIGS solar cells. However, the use of thick CdS buffer decreases the short-circuit current …

Chemical states and local structure in Cu-deficient Cu x InSe∼ 2 thin films: insights into engineering and bandgap narrowing

AY Mohamed, BG Han, H Jang, JO Jeon… - Journal of Materials …, 2023 - pubs.rsc.org
The Cu-deficient CuxInSe∼ 2 (x> 0.3) phase can be stabilized as a thin film. A uniform Cu-
deficient composition with a chalcopyrite structure was obtained by the precision …

Conduction Band Cliff at the CdS/CuIn0.1Ga0.9Se2 Thin-Film Solar Cell Interface

M Blankenship, D Hauschild, L Both… - The Journal of …, 2023 - ACS Publications
The electronic structure of a Ga-rich wide-gap CuIn0. 1Ga0. 9Se2 thin-film solar cell
absorber and its interface with a solution-grown CdS buffer layer were directly investigated …