Recent developments in the investigation of driving forces for transforming coinage metal nanoclusters

X Zou, X Kang, M Zhu - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal nanoclusters serve as an emerging class of modular nanomaterials. The
transformation of metal nanoclusters has been fully reflected in their studies from every …

Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R Jin - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Electrochemical NO3 Reduction Catalyzed by Atomically Precise Ag30Pd4 Bimetallic Nanocluster: Synergistic Catalysis or Tandem Catalysis?

L Qin, F Sun, Z Gong, G Ma, Y Chen, Q Tang, L Qiao… - ACS …, 2023 - ACS Publications
Electrochemically converting NO3–compounds into ammonia represents a sustainable route
to remove industrial pollutants in wastewater and produce valuable chemicals. Bimetallic …

Platonic and Archimedean solids in discrete metal-containing clusters

XM Luo, YK Li, XY Dong, SQ Zang - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal-containing clusters have attracted increasing attention over the past 2–3 decades.
This intense interest can be attributed to the fact that these discrete metal aggregates, whose …

Tailoring the photoluminescence of atomically precise nanoclusters

X Kang, M Zhu - Chemical Society Reviews, 2019 - pubs.rsc.org
Due to their atomically precise structures and intriguing chemical/physical properties, metal
nanoclusters are an emerging class of modular nanomaterials. Photo-luminescence (PL) is …

Endohedrally doped cage clusters

J Zhao, Q Du, S Zhou, V Kumar - Chemical Reviews, 2020 - ACS Publications
The discovery of carbon fullerene cages and their solids opened a new avenue to build
materials from stable cage clusters as “artificial atoms” or “superatoms” instead of atoms …

Chemically modified gold/silver superatoms as artificial elements at nanoscale: design principles and synthesis challenges

S Takano, T Tsukuda - Journal of the American Chemical Society, 2021 - ACS Publications
Pure and doped gold/silver clusters protected by monolayers of organic ligands have
attracted much interest as novel functional materials owing to their nonbulk-like, size-specific …

Surface chemistry of atomically precise coinage–metal nanoclusters: from structural control to surface reactivity and catalysis

J Yan, BK Teo, N Zheng - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus A comprehensive understanding of chemical bonding and reactions at the
surface of nanomaterials is of great importance in the rational design of their functional …

Doping‐Mediated Energy‐Level Engineering of M@Au12 Superatoms (M=Pd, Pt, Rh, Ir) for Efficient Photoluminescence and Photocatalysis

H Hirai, S Takano, T Nakashima… - Angewandte Chemie …, 2022 - Wiley Online Library
We synthesized a series of MAu12 (dppe) 5Cl2 (MAu12; M= Au, Pd, Pt, Rh, or Ir; dppe= 1, 2‐
bis (diphenylphosphino) ethane), which have icosahedral M@ Au12 superatomic cores, and …

Au 25 (SR) 18: the captain of the great nanocluster ship

X Kang, H Chong, M Zhu - Nanoscale, 2018 - pubs.rsc.org
Noble metal nanoclusters are in the intermediate state between discrete atoms and
plasmonic nanoparticles and are of significance due to their atomically accurate structures …