Recent advances in Sonogashira reactions

R Chinchilla, C Nájera - Chemical Society Reviews, 2011 - pubs.rsc.org
The coupling of aryl or vinyl halides with terminal acetylenes catalysed by palladium and
other transition metals, commonly termed as Sonogashira cross-coupling reaction, is one of …

Copper-free Sonogashira cross-coupling reactions: an overview

F Mohajer, MM Heravi, V Zadsirjan… - RSC advances, 2021 - pubs.rsc.org
The Sonogashira reaction is a cross-coupling reaction of a vinyl or aryl halide with a terminal
alkyne to form a C–C bond. In its original form, the Sonogashira reaction is performed with a …

A guide to Sonogashira cross-coupling reactions: the influence of substituents in aryl bromides, acetylenes, and phosphines

M Schilz, H Plenio - The Journal of Organic Chemistry, 2012 - ACS Publications
The conversion–time data for 168 different Pd/Cu-catalyzed Sonogashira cross-coupling
reactions of five arylacetylenes (phenylacetylene; 1-ethynyl-2-ethylbenzene; 1-ethynyl-2, 4 …

Recent progress and current applications of Sonogashira coupling reaction in water

M Bakherad - Applied Organometallic Chemistry, 2013 - Wiley Online Library
The use of aqueous media in palladium‐catalyzed reactions has become popular because
water‐based synthetic processes are inherently safer as well as being inexpensive …

Mechanistic exploration of the Pd-catalyzed copper-free Sonogashira reaction

M Garcia-Melchor, MC Pacheco, C Najera… - ACS …, 2012 - ACS Publications
The reaction mechanism for the Pd-catalyzed Cu-free Sonogashira reaction is analyzed by
means of density functional theory (DFT) calculations on a model system. The most common …

Green synthesis of graphene oxide (GO)-anchored Pd/Cu bimetallic nanoparticles using Ocimum sanctum as bio-reductant: an efficient heterogeneous catalyst for the …

S Sultana, SD Mech, FL Hussain, P Pahari, G Borah… - RSC …, 2020 - pubs.rsc.org
To explore the synergism between two metal centers we have synthesized graphene oxide
(GO) supported Pd/Cu@ GO, Pd@ GO and Cu@ GO nanoparticles through bio-reduction of …

Copper-Free Sonogashira coupling in water with an amphiphilic resin-supported palladium complex

T Suzuka, Y Okada, K Ooshiro, Y Uozumi - Tetrahedron, 2010 - Elsevier
The palladium-catalyzed coupling reaction of aryl halides with terminal alkynes, the
Sonogashira coupling, took place in water under copper-free conditions by use of an …

Dramatic Impact of ppb Levels of Palladium on the “Copper‐Catalyzed” Sonogashira Coupling

Z Gonda, GL Tolnai, Z Novák - Chemistry–A European Journal, 2010 - infona.pl
Palladacadabra! The effect of ppb levels of palladium on the “copper‐catalyzed”
Sonogashira coupling is reported. The observed high sensitivity to palladium impurities …

Green and convenient protocols for the efficient reduction of nitriles and nitro compounds to corresponding amines with NaBH 4 in water catalyzed by magnetically …

B Zeynizadeh, F Mohammad Aminzadeh… - Research on Chemical …, 2019 - Springer
In this study, firstly, CuFe 2 O 4 nanoparticles were prepared by a simple operation. The
structure of the mentioned nanoparticles was characterized by Fourier transform infrared …

N-Heterocyclic carbene-catalyzed 1, 3-dipolar cycloaddition reactions: a facile synthesis of 3, 5-di-and 3, 4, 5-trisubstituted isoxazoles

S Kankala, R Vadde, CS Vasam - Organic & biomolecular chemistry, 2011 - pubs.rsc.org
A first example of organo-N-heterocyclic carbene (NHC) catalyzed click-type fast 1, 3-dipolar
cycloaddition of nitrile oxides with alkynes was developed for the regioselective synthesis of …