A review of degradation mechanisms and recent achievements for Ni‐rich cathode‐based Li‐ion batteries

M Jiang, DL Danilov, RA Eichel… - Advanced Energy …, 2021 - Wiley Online Library
The growing demand for sustainable energy storage devices requires rechargeable lithium‐
ion batteries (LIBs) with higher specific capacity and stricter safety standards. Ni‐rich layered …

Challenges and strategies towards single‐crystalline Ni‐rich layered cathodes

L Ni, S Zhang, A Di, W Deng, G Zou… - Advanced energy …, 2022 - Wiley Online Library
The ever‐increasing energy density requirements in electric vehicles (EVs) have boosted
the development of Ni‐rich layered oxide cathodes for state‐of‐the‐art lithium‐ion batteries …

Origin of structural degradation in Li-rich layered oxide cathode

T Liu, J Liu, L Li, L Yu, J Diao, T Zhou, S Li, A Dai… - Nature, 2022 - nature.com
Li-and Mn-rich (LMR) cathode materials that utilize both cation and anion redox can yield
substantial increases in battery energy density,–. However, although voltage decay issues …

Enabling high energy lithium metal batteries via single-crystal Ni-rich cathode material co-doping strategy

X Ou, T Liu, W Zhong, X Fan, X Guo, X Huang… - Nature …, 2022 - nature.com
High-capacity Ni-rich layered oxides are promising cathode materials for secondary lithium-
based battery systems. However, their structural instability detrimentally affects the battery …

Stalling oxygen evolution in high-voltage cathodes by lanthurization

M Cai, Y Dong, M Xie, W Dong, C Dong, P Dai… - Nature Energy, 2023 - nature.com
Coatings and surface passivation are sought to protect high-energy-density cathodes in
lithium-ion batteries, which suffer from labile oxygen loss and fast degradations. Here we …

Capacity fading mechanisms in Ni-rich single-crystal NCM cathodes

HH Ryu, B Namkoong, JH Kim, I Belharouak… - ACS Energy …, 2021 - ACS Publications
A series of single-crystal, Ni-rich Li [Ni x Co y Mn1–x–y] O2 (NCM) cathodes (x= 0.7, 0.8, and
0.9) with particle diameters of∼ 3 μm are systematically compared with polycrystalline …

Ultra-high-voltage Ni-rich layered cathodes in practical Li metal batteries enabled by a sulfonamide-based electrolyte

W Xue, M Huang, Y Li, YG Zhu, R Gao, X Xiao… - Nature Energy, 2021 - nature.com
By increasing the charging voltage, a cell specific energy of> 400 W h kg− 1 is achievable
with LiNi0. 8Mn0. 1Co0. 1O2 in Li metal batteries. However, stable cycling of high-nickel …

Phase-engineered cathode for super-stable potassium storage

L Wu, H Fu, S Li, J Zhu, J Zhou, AM Rao, L Cha… - Nature …, 2023 - nature.com
The crystal phase structure of cathode material plays an important role in the cell
performance. During cycling, the cathode material experiences immense stress due to …

A nonflammable electrolyte for ultrahigh-voltage (4.8 V-class) Li|| NCM811 cells with a wide temperature range of 100 C

P Xiao, Y Zhao, Z Piao, B Li, G Zhou… - Energy & Environmental …, 2022 - pubs.rsc.org
The development of ultrahigh-voltage lithium metal batteries is one of the most promising
ways to increase the energy density. However, commercial ethylene carbonate (EC)-based …

Fundamental and solutions of microcrack in Ni-rich layered oxide cathode materials of lithium-ion batteries

S Yin, W Deng, J Chen, X Gao, G Zou, H Hou, X Ji - Nano Energy, 2021 - Elsevier
Ni-rich layered transition metal oxide is one of the most promising cathode materials for the
next generation lithium-based automotive batteries due to its excellent electrochemical …