The late stage functionalization (LSF) of complex biorelevant compounds is a powerful tool
to speed up the identification of structure–activity relationships (SARs) and to optimize …

The mainstream applications of visible‐light photoredox catalysis predominately involve
outer‐sphere single‐electron transfer (SET) or energy transfer (EnT) processes of precious …

Azetidines are prominent structural scaffolds in bioactive molecules, medicinal chemistry,
and ligand design for transition metals. However, state-of-the-art methods cannot be applied …

We demonstrate Markovnikov hydroalkoxylation of unactivated alkenes using alcohols
through a triple catalysis consisting of photoredox, cobalt, and Brønsted acid catalysts under …

Catalytic hydrogen atom transfer from metal‐hydrides to alkenes allows feedstock olefins to
be used as alkyl radical precursors. The chemoselectivity of this process makes it an …

The hydrofluorination of alkenes represents an attractive strategy for the synthesis of
aliphatic fluorides. This approach provides a direct means to form C (sp3)–F bonds …

An efficient and general radical hydroamination of alkenes using Co (salen) as catalyst, N‐
fluorobenzenesulfonimide (NFSI) and its analogues as both nitrogen source and oxidant …

A Markovnikov-selective hydroacylation of alkenes has been achieved via the synergistic
merger cobalt, photoredox and N-heterocyclic carbene catalysis. The closely incorporated …

Oxidative MHAT hydrofunctionalization of alkenes provides a mild cobalt-catalyzed route to
forming C–N and C–O bonds. Here, we characterize relevant salen-supported cobalt …

Catalytic asymmetric hydroamination of alkenes with Lewis basic amines is of great interest
but remains a challenge in synthetic chemistry. Here, we developed a Co‐catalyzed …