Periodic trends in gas–phase oxidation and hydrogenation reactions of lanthanides and 5d transition metal cations

PB Armentrout - Mass Spectroscopy Reviews, 2021 - osti.gov
Of the many publications coming from the laboratory of Diethard K. Bohme, among the most
valuable were the surveys of reactivity throughout the periodic table as studied using …

Quantitative Aspects of Gas-Phase Metal Ion Chemistry: Conservation of Spin, Participation of f Orbitals, and C–H Activation and C–C Coupling

PB Armentrout - The Journal of Physical Chemistry A, 2023 - ACS Publications
In this Featured Article, I reflect on over 40 years of guided ion beam tandem mass
spectrometry (GIBMS) studies involving atomic metal cations and their clusters throughout …

Utilizing metal cation reactions with carbonyl sulfide to remove isobaric interferences in tandem inductively coupled plasma mass spectrometry analyses

AD French, KM Melby, RM Cox, E Bylaska… - … Acta Part B: Atomic …, 2023 - Elsevier
Carbonyl sulfide (OCS) was used as a reaction gas to investigate gas phase metal (M+) ion-
molecule reactions using the Agilent 8900 inductively coupled plasma tandem mass …

[HTML][HTML] Determination of the SmO+ bond energy by threshold photodissociation of the cryogenically cooled ion

A Lachowicz, EH Perez, NS Shuman, SG Ard… - The Journal of …, 2021 - pubs.aip.org
The SmO+ bond energy has been measured by monitoring the threshold for
photodissociation of the cryogenically cooled ion. The action spectrum features a very sharp …

f-Block reactions of metal cations with carbon dioxide studied by inductively coupled plasma tandem mass spectrometry

RM Cox, KM Melby, AD French… - Physical Chemistry …, 2024 - pubs.rsc.org
f-Block chemistry offers an opportunity to test current knowledge of chemical reactivity. The
energy dependence of lanthanide cation (Ln+= Ce+, Pr+, Nd+–Eu+) and actinide cation …

Gas-phase ion-molecule interactions in a collision reaction cell with triple quadrupole-inductively coupled plasma mass spectrometry: Investigations with N2O as the …

K Harouaka, C Allen, E Bylaska, RM Cox… - … Acta Part B: Atomic …, 2021 - Elsevier
Nitrous oxide (N 2 O) was used as a reaction gas to investigate the gas-phase ion-molecule
interactions using the Agilent 8900 QQQ-ICP-MS. A multi-element standard containing 45 …

Guided Ion Beam Studies of the Dy + O → DyO+ + e Chemi-ionization Reaction Thermochemistry and Dysprosium Oxide, Carbide, Sulfide, Dioxide, and Sulfoxide …

M Ghiassee, EG Christensen, T Fenn… - The Journal of …, 2022 - ACS Publications
Guided ion beam tandem mass spectrometry (GIBMS) was used to measure the kinetic
energy dependent product ion cross sections for reactions of the lanthanide metal …

A Common Bottleneck for Metal Oxidation by Molecular Oxygen Across Size Regimes: Kinetics of Atomic Lanthanide Cations (La+–Lu+) with O2

SG Ard, BC Sweeny, TWR Lewis, BA Long… - The Journal of …, 2024 - ACS Publications
Kinetics of the lanthanide cations (Ln+= La+–Lu+ excluding Pm+) reacting with molecular
oxygen were measured in a selected-ion flow tube apparatus from 300 to 600 K. Where …

Relativistic internally contracted multireference electron correlation methods

T Shiozaki, W Mizukami - Journal of chemical theory and …, 2015 - ACS Publications
We report internally contracted relativistic multireference configuration interaction (ic-MRCI),
complete active space second-order perturbation (CASPT2), and strongly contracted n …

Evaluation of the Pr+ O→ PrO++ e− chemi-ionization reaction enthalpy and praseodymium oxide, carbide, dioxide, and carbonyl cation bond energies

M Ghiassee, BC Stevenson… - Physical Chemistry …, 2021 - pubs.rsc.org
Guided ion beam tandem mass spectrometry (GIBMS) was used to measure the kinetic
energy dependent product ion cross sections for reactions of the lanthanide metal …