% V Bur index and steric maps: from predictive catalysis to machine learning

S Escayola, N Bahri-Laleh, A Poater - Chemical Society Reviews, 2024 - pubs.rsc.org
Steric indices are parameters used in chemistry to describe the spatial arrangement of
atoms or groups of atoms in molecules. They are important in determining the reactivity …

Ring Opening Polymerization of Six-and Eight-Membered Racemic Cyclic Esters for Biodegradable Materials

A Grillo, Y Rusconi, MC D'Alterio, C De Rosa… - International Journal of …, 2024 - mdpi.com
The low percentage of recyclability of the polymeric materials obtained by olefin transition
metal (TM) polymerization catalysis has increased the interest in their substitution with more …

In-situ photo-crosslinkable elastomer based on polyalphaolefin/halloysite nanohybrid

SSA Kheljani, K Didehban, M Atai, C Zou… - Journal of Colloid and …, 2024 - Elsevier
In this research, new injectable and in situ photocurable elastomeric nanohybrids have been
fabricated from polyalphaolefin (PAO) resins and halloysite nanofiller. In this regard, the co …

Influence of the reaction conditions on the Ziegler-Natta catalyzed ethylene polymerization: Kinetics and properties of the resulting polymers

N Moeini, H Teimoury, M Salimi, N Bahri-Laleh… - Polymer, 2024 - Elsevier
This work conducts an investigation into how the polymerization conditions affect the kinetics
of ethylene homopolymerization and the properties of the final polyethylene using a …

Tuning the steric hindrance of alkylamines: a predictive model of steric editing of planar amines

M Tomasini, M Voccia, L Caporaso, M Szostak… - Chemical …, 2024 - pubs.rsc.org
Amines are one of the most prevalent functional groups in chemistry. Perhaps even more
importantly, amines represent one of the most ubiquitous moieties within the realm of …

Rhenium Alkyne Catalysis: Sterics Control the Reactivity

M Tomasini, M Gimferrer, L Caporaso… - Inorganic …, 2024 - ACS Publications
Metathesis reactions, including alkane, alkene, and alkyne metatheses, have their origins in
the fundamental understanding of chemical reactions and the development of specialized …

Computational Insights into the Regioselectivity of 1, 3-Dipolar Cycloadditions inside Carbon Nanotubes

M Tomasini, TD Marforio, M Calveresi… - The Journal of …, 2024 - ACS Publications
Nature's enzymes exhibit remarkable substrate specificity and catalytic efficiency by
transforming substrates within confined active sites. To emulate this, various molecular …

Hydrogen autotransfer with alcohols for alkylations

N Joly, S Gaillard, A Poater, JL Renaud - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
Despite the advancements enabled by organometallic complexes in organic synthesis,
which have led to innovative transformations and tackled issues related to waste and atom …

[HTML][HTML] New halloysite-supported bio-based acidic ionic liquid as an efficient catalyst for conversion of fructose to 5-hydroxymethylfurfural: A combined experimental …

S Sadjadi, M Fahimizadeh, N Bahri-Laleh… - Journal of Molecular …, 2024 - Elsevier
In an effort to design a bio-based catalyst with enough acidic strength to promote the
conversion of fructose to 5-hydroxymethylfurfural, a series of halloysite clay-supported acidic …

[HTML][HTML] A green approach to synthesize polybutene lubricants from mixed C4 monomers using supported dendritic ionic liquids

A Ghavampoor, N Bahri-Laleh, S Sadjadi… - Journal of Molecular …, 2024 - Elsevier
Lubricants, composed of a base oil and various additives, reduce friction and abrasion
between moving surfaces. High-performance lubricants, especially in the automotive and …