Photomechanical properties in metal–organic crystals

S Khan, MH Mir - Chemical Communications, 2024 - pubs.rsc.org
The emergence of materials that can effectively convert photon energy (light) into motion
(mechanical work) and change their shapes on command is of great interest for their …

Construction of olefinic coordination polymer single crystal platforms: precise organic synthesis, in situ exploration of reaction mechanisms and beyond

Q Zhang, Y Wang, P Braunstein, JP Lang - Chemical Society Reviews, 2024 - pubs.rsc.org
Olefin [2+ 2] photocycloaddition reactions based on coordination-bond templates provide
numerous advantages for the selective synthesis of cyclobutane compounds. This review …

Visible Light‐fueled Mechanical Motions with Dynamic Phosphorescence Induced by Topochemical [2+ 2] Reactions in Organoboron Crystals

S Bhandary, M Beliš, L Bourda… - Angewandte Chemie …, 2023 - Wiley Online Library
In the quest for essential energy solutions towards an ecological friendly future, the
transformation of visible light/solar energy into mechanical motions in metal‐free …

Construction of Photoreactive Chiral Metal–Organic Frameworks and Their [2+ 2] Photocycloaddition Reactions

S Kim, J An, H Choi, SH Jung, SS Lee… - Inorganic Chemistry, 2023 - ACS Publications
Chiral metal–organic frameworks (CMOFs) and solid-state [2+ 2] photocyclization have been
explored as independent areas in crystal engineering. We herein report the photoreactive …

Recent Advances in Photomechanical Crystals Made from Metal–Organic and Organometallic Complexes

YL Chen, YG Wang, Q Yu - Organometallics, 2023 - ACS Publications
Photomechanical crystals that can directly convert light energy into mechanical work
attracted increasing attention due to their dramatic behaviors and potential applications in …

A dual-functional 2D coordination polymer exhibiting photomechanical and electrically conductive behaviours

S Khan, P Das, S Naaz, P Brandão, A Choudhury… - Dalton …, 2023 - pubs.rsc.org
A photoactive two-dimensional coordination polymer (2D CP)[Zn2 (4-spy) 2 (bdc) 2] n (1)[4-
spy= 4-styrylpyridine and H2bdc= 1, 4-benzendicarboxylic acid] undergoes a photochemical …

[HTML][HTML] [2+ 2] Photocycloaddition Reaction as A Tool to Monitor the Molecular Motions in the Solid State by Mechanochemical Grinding

JJ Vittal - Journal of Photochemistry and Photobiology C …, 2023 - Elsevier
Mechanochemistry, a burgeoning field in green chemistry, has been utilized frequently to
synthesize various organic molecules, metal complexes, coordination polymers (CPs) and …

Photomechanical effects based on a one-dimensional Zn coordination polymer crystal driven by [4+ 4] cycloaddition

Y Chen, C Yu, X Zhu, Q Yu - Dalton Transactions, 2023 - pubs.rsc.org
Photomechanical crystals are promising candidates for photo actuators due to their ability to
convert light energy into mechanical energy. We synthesized a coordination polymer crystal …

Bending, Twisting, and Propulsion of Photoreactive Crystals by Controlled Gas Release

C Yu, X Jiang, MB Al‐Handawi… - Angewandte Chemie …, 2024 - Wiley Online Library
The rapid release of gas by a chemical reaction to generate momentum is one of the most
fundamental ways to elicit motion that could be used to sustain and control the motility of …

Impact of halogen⋯ halogen interaction on the mechanical motion of a 3D Pb (ii) coordination polymer of elusive topology

S Khan, S Naaz, S Ahmad, RM Gomila… - Chemical …, 2024 - pubs.rsc.org
Herein, we report the synthesis of a Pb (II) based three-dimensional coordination polymer
(3D CP),[Pb (DCTP)] n (1)[H2DCTP= 2, 5-dichloroterephthalic acid] with an unprecedented …