Photomechanical properties in metal–organic crystals
The emergence of materials that can effectively convert photon energy (light) into motion
(mechanical work) and change their shapes on command is of great interest for their …
(mechanical work) and change their shapes on command is of great interest for their …
Construction of olefinic coordination polymer single crystal platforms: precise organic synthesis, in situ exploration of reaction mechanisms and beyond
Q Zhang, Y Wang, P Braunstein, JP Lang - Chemical Society Reviews, 2024 - pubs.rsc.org
Olefin [2+ 2] photocycloaddition reactions based on coordination-bond templates provide
numerous advantages for the selective synthesis of cyclobutane compounds. This review …
numerous advantages for the selective synthesis of cyclobutane compounds. This review …
Visible Light‐fueled Mechanical Motions with Dynamic Phosphorescence Induced by Topochemical [2+ 2] Reactions in Organoboron Crystals
S Bhandary, M Beliš, L Bourda… - Angewandte Chemie …, 2023 - Wiley Online Library
In the quest for essential energy solutions towards an ecological friendly future, the
transformation of visible light/solar energy into mechanical motions in metal‐free …
transformation of visible light/solar energy into mechanical motions in metal‐free …
Construction of Photoreactive Chiral Metal–Organic Frameworks and Their [2+ 2] Photocycloaddition Reactions
S Kim, J An, H Choi, SH Jung, SS Lee… - Inorganic Chemistry, 2023 - ACS Publications
Chiral metal–organic frameworks (CMOFs) and solid-state [2+ 2] photocyclization have been
explored as independent areas in crystal engineering. We herein report the photoreactive …
explored as independent areas in crystal engineering. We herein report the photoreactive …
Recent Advances in Photomechanical Crystals Made from Metal–Organic and Organometallic Complexes
YL Chen, YG Wang, Q Yu - Organometallics, 2023 - ACS Publications
Photomechanical crystals that can directly convert light energy into mechanical work
attracted increasing attention due to their dramatic behaviors and potential applications in …
attracted increasing attention due to their dramatic behaviors and potential applications in …
A dual-functional 2D coordination polymer exhibiting photomechanical and electrically conductive behaviours
A photoactive two-dimensional coordination polymer (2D CP)[Zn2 (4-spy) 2 (bdc) 2] n (1)[4-
spy= 4-styrylpyridine and H2bdc= 1, 4-benzendicarboxylic acid] undergoes a photochemical …
spy= 4-styrylpyridine and H2bdc= 1, 4-benzendicarboxylic acid] undergoes a photochemical …
[HTML][HTML] [2+ 2] Photocycloaddition Reaction as A Tool to Monitor the Molecular Motions in the Solid State by Mechanochemical Grinding
JJ Vittal - Journal of Photochemistry and Photobiology C …, 2023 - Elsevier
Mechanochemistry, a burgeoning field in green chemistry, has been utilized frequently to
synthesize various organic molecules, metal complexes, coordination polymers (CPs) and …
synthesize various organic molecules, metal complexes, coordination polymers (CPs) and …
Photomechanical effects based on a one-dimensional Zn coordination polymer crystal driven by [4+ 4] cycloaddition
Y Chen, C Yu, X Zhu, Q Yu - Dalton Transactions, 2023 - pubs.rsc.org
Photomechanical crystals are promising candidates for photo actuators due to their ability to
convert light energy into mechanical energy. We synthesized a coordination polymer crystal …
convert light energy into mechanical energy. We synthesized a coordination polymer crystal …
Bending, Twisting, and Propulsion of Photoreactive Crystals by Controlled Gas Release
C Yu, X Jiang, MB Al‐Handawi… - Angewandte Chemie …, 2024 - Wiley Online Library
The rapid release of gas by a chemical reaction to generate momentum is one of the most
fundamental ways to elicit motion that could be used to sustain and control the motility of …
fundamental ways to elicit motion that could be used to sustain and control the motility of …
Impact of halogen⋯ halogen interaction on the mechanical motion of a 3D Pb (ii) coordination polymer of elusive topology
Herein, we report the synthesis of a Pb (II) based three-dimensional coordination polymer
(3D CP),[Pb (DCTP)] n (1)[H2DCTP= 2, 5-dichloroterephthalic acid] with an unprecedented …
(3D CP),[Pb (DCTP)] n (1)[H2DCTP= 2, 5-dichloroterephthalic acid] with an unprecedented …