Metal-insulator transitions

M Imada, A Fujimori, Y Tokura - Reviews of modern physics, 1998 - APS
Metal-insulator transitions are accompanied by huge resistivity changes, even over tens of
orders of magnitude, and are widely observed in condensed-matter systems. This article …

Multiplet effects in X-ray spectroscopy

F De Groot - Coordination Chemistry Reviews, 2005 - Elsevier
This review gives an overview of the presence of multiplet effects in X-ray spectroscopy, with
an emphasis on X-ray absorption studies on 3d transition metal ions in inorganic oxides and …

Transition metal oxide work functions: the influence of cation oxidation state and oxygen vacancies

MT Greiner, L Chai, MG Helander… - Advanced Functional …, 2012 - Wiley Online Library
Transition metal oxides are capable of a wide range of work functions. This quality allows
them to be used in many applications that involve charge transfer with adsorbed molecules …

Mixed-valence vanadium oxides studied by XPS

M Demeter, M Neumann, W Reichelt - Surface Science, 2000 - Elsevier
We have investigated several mixed-valence vanadium oxides, single-crystals by X-ray
photoelectron spectroscopy (XPS). Many studies have been performed on V2O5, VO2 and …

Electronic structure of studied by photoemission and x-ray-absorption spectroscopy

T Saitoh, AE Bocquet, T Mizokawa, H Namatame… - Physical Review B, 1995 - APS
The electronic structure of La 1− x Sr x MnO 3 has been studied by photoemission and O 1s
x-ray-absorption spectroscopy. Spectra of the Mn 2p core levels and the valence bands for …

Electronic structure and orbital ordering in perovskite-type 3d transition-metal oxides studied by Hartree-Fock band-structure calculations

T Mizokawa, A Fujimori - Physical Review B, 1996 - APS
We have studied transition-metal 3d-oxygen 2p lattice models, where full degeneracy of
transition-metal 3d and oxygen 2p orbitals and on-site Coulomb and exchange interactions …

Electronic structure of early 3d-transition-metal oxides by analysis of the 2p core-level photoemission spectra

AE Bocquet, T Mizokawa, K Morikawa, A Fujimori… - Physical Review B, 1996 - APS
The electronic structures of a wide range of early transition-metal (TM) compounds,
including Ti and V oxides with metal valences ranging from 2+ to 5+ and formal d-electron …

Electronic structure of 3d-transition-metal oxides: on-site Coulomb repulsion versus covalency

R Zimmermann, P Steiner, R Claessen… - Journal of Physics …, 1999 - iopscience.iop.org
We have performed photoemission and inverse photoemission experiments on a series of
3d-transition-metal oxides with formal ionic configuration from to. The photoemission core …

Optical spectra in (La,Y): Variation of Mott-Hubbard gap features with change of electron correlation and band filling

Y Okimoto, T Katsufuji, Y Okada, T Arima, Y Tokura - Physical Review B, 1995 - APS
Optical spectra have been investigated for the prototypical Mott-Hubbard (MH) insulators
LaTiO 3 and YTiO 3, and their solid solutions La x Y 1− x TiO 3. The MH gap shows a critical …

Strong hybridization in vanadium oxides: evidence from photoemission and absorption spectroscopy

R Zimmermann, R Claessen, F Reinert… - Journal of Physics …, 1998 - iopscience.iop.org
We present x-ray photoemission spectra of the vanadium oxides, and, and their analysis in
terms of a simple cluster model based on the Anderson impurity Hamiltonian. The electronic …