Alkali Metal Carbatrane Compounds [TismPriBenz]M: Synthesis and Structural Characterization of a Complete Series of Monomeric Alkali Metal Alkyl Compounds

DA Vaccaro, G Parkin - Organometallics, 2023 - ACS Publications
The tris [(1-isopropylbenzimidazol-2-yl) dimethylsilyl] methyl thallium compound,[
TismPriBenz] Tl, reacts with Li, Na, K, and Rb to afford the respective alkali metal carbatrane …

Redox activity and π bonding in a tripodal seven-coordinate molybdenum (VI) tris (amidophenolate)

T Marshall-Roth, SN Brown - Dalton Transactions, 2015 - pubs.rsc.org
A tris (aminophenol), tris (2-(3′, 5′-di-tert-butyl-2′-hydroxyphenyl) amino-4-
methylphenyl) amine, MeClampH6, is prepared in three steps from tri-p-tolylamine. The …

Tris [(1-isopropylbenzimidazol-2-yl) dimethylsilyl] methyl metal complexes,[Tism PriBenz] M: a new class of metallacarbatranes, isomerization to a tris (N-heterocyclic …

S Ruccolo, M Rauch, G Parkin - Chemical Science, 2017 - pubs.rsc.org
The tris [(1-isopropylbenzimidazol-2-yl) dimethylsilyl] methyl ligand,[TismPriBenz], has been
employed to form carbatrane compounds of both the main group metals and transition …

Second-coordination-sphere assisted selective colorimetric turn-on fluoride sensing by a mono-metallic Co (II) hexacarboxamide cryptand complex

JM Stauber, GE Alliger, DG Nocera… - Inorganic …, 2017 - ACS Publications
The preparation of a selective turn-on colorimetric fluoride sensor was achieved through
single cobalt (II) ion insertion into a macrobicyclic cryptand. Monometallic [Co (m BDCA-5t …

Synthesis, structure, and physical properties for a series of trigonal bipyramidal M II–Cl complexes with intramolecular hydrogen bonds

NS Sickerman, YJ Park, GKY Ng, JE Bates… - Dalton …, 2012 - pubs.rsc.org
A series of transition metal chloro complexes with the tetradentate tripodal tris (2-amino-
oxazoline) amine ligand (TAO) have been synthesized and characterized. X-Ray structural …

Structural characterization of tris (pyrazolyl) hydroborato and tris (2-pyridylthio) methyl lithium compounds: Lithium in uncommon trigonal pyramidal and trigonal …

N Chakrabarti, W Sattler, G Parkin - Polyhedron, 2013 - Elsevier
X-ray diffraction reveals that the molecular structures of the tris (pyrazolyl) hydroborato and
tris (2-pyridylthio) methyl lithium compounds,[[Formula: see text]] Li (R= H, Me) and [κ4-Tptm] …

Synthesis and structural features of Co (II) and Co (III) complexes supported by aminotrisphenolate ligand scaffolds

C Martín, CJ Whiteoak, E Martin… - Inorganic …, 2014 - ACS Publications
Co (II) complexes of aminotrisphenolate ((ArO) 3N3–) ligands can be prepared
straightforwardly in high yield. X-ray analysis reveals these complexes to comprise of two …

Synthesis and structural characterization of tris (pyrazolyl) hydroaluminate and tris (pyrazolyl) hydrogallate lithium compounds

D Sambade, G Parkin - Polyhedron, 2017 - Elsevier
The tris (pyrazolyl) hydroaluminate derivatives,[HAlTp Bu t, Me] Li and {[HAlTp Me 2] Li} 2,
have been synthesized via the reactions of LiAlH 4 with 3-tert-butyl-5-methylpyrazole and 3 …

Synthesis and reactivity of tripodal complexes containing pendant bases

JM Blacquiere, ML Pegis, S Raugei… - Inorganic …, 2014 - ACS Publications
The synthesis of a new tripodal ligand family that contains tertiary amine groups in the
second-coordination sphere is reported. The ligands are tris (amido) amine derivatives, with …

Different geometries of novel cobalt (II) compounds with 2-hydroxy-benzophenones and neocuproine: Crystal and molecular structures of [Co (2-hydroxy …

M Lalia-Kantouri, CD Papadopoulos, AG Hatzidimitriou… - Polyhedron, 2013 - Elsevier
Ten mixed-ligand Co (II) compounds with 2-hydroxy-benzophenones (ketones) and
neocuproine (neoc) were synthesized and characterized by physicochemical and spectral …