Investigation of new methods for the synthesis of C–C bonds is fundamental for the
development of new organic drugs and materials. Aryl-, alkenyl-and alkynylboronic acids …

A copper‐based complex that contains a sulfonate N‐heterocyclic carbene ligand was first
reported 15 years ago. Since then, these organometallic entities have proven to be uniquely …

Introducing self-assembly strategies into the construction of catalysts has been proven to
have great advantages in asymmetric catalysis. We constructed two chiral metalla-triangles …

A series of chiral binaphthyl-based conjugated polymers enantiomers incorporating boron
dipyrromethene (BODIPY) chromophore in the main chain backbone were designed and …

Bis‐heteroaryl or bis‐aryl stereocenters were formed by an organocatalytic enantioselective
conjugate addition using the respective trifluoroborate salts as nucleophiles. Control studies …

Copper complexes of phosphoramidites efficiently catalyzed asymmetric addition of
arylboron reagents to acyclic enones. Importantly, rare 1, 4-insertion of arylcopper (I) was …

Despite a recent publication describing boronic acids as a “novel class of bacterial
mutagen,” process and analytical chemists may not be aware of the potential worker …

In recent years, palladium‐catalyzed direct arylation of (hetero) aromatics with aryl halides
through a C H bond activation has become a popular method for generating carbon …

Chiral biphenols catalyze the asymmetric Petasis borono‐Mannich allylation of aldehydes
and amines through the use of a bench‐stable allyldioxaborolane. The reaction proceeds …

1, 1′-Bi-2-naphthol (BINOL) has been extensively used as the chirality source in the fields
of molecular recognition, asymmetric synthesis, and materials science. The direct …