Replacement of less-preferred dipolar aprotic and ethereal solvents in synthetic organic chemistry with more sustainable alternatives

A Jordan, CGJ Hall, LR Thorp, HF Sneddon - Chemical reviews, 2022 - ACS Publications
Dipolar aprotic and ethereal solvents comprise just over 40% of all organic solvents utilized
in synthetic organic, medicinal, and process chemistry. Unfortunately, many of the common …

The Hofmeister effect and the behaviour of water at interfaces

KD Collins, MW Washabaugh - Quarterly reviews of biophysics, 1985 - cambridge.org
Starting from known properties of non-specific salt effects on the surface tension at an air–
water interface, we propose the first general, detailed qualitative molecular mechanism for …

Bicyclic-ring base doping induces n-type conduction in carbon nanotubes with outstanding thermal stability in air

S Horike, Q Wei, K Akaike, K Kirihara… - Nature …, 2022 - nature.com
The preparation of air and thermally stable n-type carbon nanotubes is desirable for their
further implementation in electronic and energy devices that rely on both p-and n-type …

The acceptor number—A quantitative empirical parameter for the electrophilic properties of solvents

U Mayer, V Gutmann, W Gerger - Monatshefte für Chemie/Chemical …, 1975 - Springer
The electrophilic properties of 34 solvents have been characterized by the Acceptor Number
(AN) which has been derived from 31 Pn. mr measurements of triethylphosphine oxide …

[图书][B] Enzymes

M Dixon, EC Webb - 1960 - books.google.com
Page 1 The Enzymes THIRD EDITION Edited by Paul D. Boyer X Protein Synthesis DNA
Synthesis and Repair RNA Synthesis Energy-Linked ATPases Synthetases Page 2 The …

Selective dissolution of halide perovskites as a step towards recycling solar cells

BJ Kim, DH Kim, SL Kwon, SY Park, Z Li, K Zhu… - Nature …, 2016 - nature.com
Most research on perovskite solar cells has focused on improving power-conversion
efficiency and stability. However, if one could refurbish perovskite solar cells, their stability …

The factors determining nucleophilic reactivities

JO Edwards, RG Pearson - Journal of the American Chemical …, 1962 - ACS Publications
Three important factors determining the reactivity of nucleophilic reagents are considered.
These are basicity, polarizabil-ity and the presence of unshared pairs of electrons on the …

Protic-dipolar aprotic solvent effects on rates of bimolecular reactions

AJ Parker - Chemical Reviews, 1969 - ACS Publications
Bimolecular reactions (see eq 1 below) between anions and uncharged species, as well as
some bimolecular reactions of other charge types, are often very much faster in dipolar …

Study of the solvent effect on the enthalpies of homolytic and heterolytic N–H bond cleavage in p-phenylenediamine and tetracyano-p-phenylenediamine

J Rimarčík, V Lukeš, E Klein, M Ilčin - Journal of Molecular Structure …, 2010 - Elsevier
In this article, we have studied p-phenylenediamine (PPD) and tetracyano-p-
phenylenediamine (TCPPD) molecules in order to study the effect of CN groups and the …

The solvent dimethyl sulfoxide

D Martin, A Weise, HJ Niclas - … Chemie International Edition in …, 1967 - Wiley Online Library
The dipolar aprotic solvent dimethyl sulfoxide is liquid over a wide range of temperatures, is
a strong electron donor, and has a high polarity. It is therefore an excellent and selective …