Toward stimuli‐responsive dynamic thermosets through continuous development and improvements in covalent adaptable networks (CANs)
M Podgórski, BD Fairbanks, BE Kirkpatrick… - Advanced …, 2020 - Wiley Online Library
Covalent adaptable networks (CANs), unlike typical thermosets or other covalently
crosslinked networks, possess a unique, often dormant ability to activate one or more forms …
crosslinked networks, possess a unique, often dormant ability to activate one or more forms …
On the welding of vitrimers: Chemistry, mechanics and applications
Linear chains in thermoplastics make them relatively weak in performance but inherently
weldable and recyclable. By contrast, thermosets with permanently crosslinked networks …
weldable and recyclable. By contrast, thermosets with permanently crosslinked networks …
Linear viscoelasticity and flow of self-assembled vitrimers: the case of a polyethylene/dioxaborolane system
RG Ricarte, F Tournilhac, M Cloître, L Leibler - Macromolecules, 2020 - ACS Publications
For vitrimer systems obtained by dynamic cross-linking of polymer chains, incompatibility
effects between the cross-links and polymer backbone can lead to microphase separation …
effects between the cross-links and polymer backbone can lead to microphase separation …
Self-healing and polymer welding of soft and stiff epoxy thermosets via silanolates
AA Putnam-Neeb, JM Kaiser, AM Hubbard… - … Composites and Hybrid …, 2022 - Springer
Incorporating dynamic bonds into polymers enables static thermosets to be transformed into
active materials, possessing the reprocessability of thermoplastics while maintaining the …
active materials, possessing the reprocessability of thermoplastics while maintaining the …
Solvent assisted pressure-free surface welding and reprocessing of malleable epoxy polymers
Covalent adaptable networks (CANs; also known as dynamic covalent networks or vitrimers)
are appealing for developing simple and efficient techniques for recycling thermosetting …
are appealing for developing simple and efficient techniques for recycling thermosetting …
Recyclable high-performance epoxy based on transesterification reaction
L Lu, J Pan, G Li - Journal of Materials Chemistry A, 2017 - pubs.rsc.org
Self-healing thermoset epoxy based on dynamic covalent bond chemistry has been
developed in the past several years, which warrants the creation of recyclable epoxy …
developed in the past several years, which warrants the creation of recyclable epoxy …
Active composites based on shape memory polymers: overview, fabrication methods, applications, and future prospects
Shape memory polymers (SMPs) have received immense attention from materials research
community thanks to their unrivaled properties such as high recoverable strains (up to …
community thanks to their unrivaled properties such as high recoverable strains (up to …
Interfacial welding of dynamic covalent network polymers
Dynamic covalent network (or covalent adaptable network) polymers can rearrange their
macromolecular chain network by bond exchange reactions (BERs) where an active unit …
macromolecular chain network by bond exchange reactions (BERs) where an active unit …
Adaptable interlocking macromolecular networks with homogeneous architecture made from immiscible single networks
WL Peng, Y You, P Xie, MZ Rong, MQ Zhang - Macromolecules, 2020 - ACS Publications
Traditional interpenetrating polymer networks (IPNs) are not adaptable materials because
the topological structure of the macromolecules cannot be changed, which limits their …
the topological structure of the macromolecules cannot be changed, which limits their …
Dissolution of epoxy thermosets via mild alcoholysis: the mechanism and kinetics study
Thermoset dissolution based on degradable bond or exchange reaction has been recently
utilized to achieve thermosetting polymer dissolution and recycling. In this paper, an …
utilized to achieve thermosetting polymer dissolution and recycling. In this paper, an …