Sultams: recent syntheses and applications

S Debnath, S Mondal - European Journal of Organic Chemistry, 2018 - Wiley Online Library
Sultams are very important scaffolds both in medicinal chemistry and in synthetic organic
chemistry. Very important methodologies for the asymmetric and non‐asymmetric synthesis …

Cesium carbonate as a mediated inorganic base in some organic transformations

R Rabie, MM Hammouda, KM Elattar - Research on Chemical …, 2017 - Springer
Cesium carbonate is a type of alkali carbonate salt having a remarkable number of
applications and has been demonstrated to be a mild inorganic base in organic synthesis. It …

Photoinduced radical cascade cyclization: A metal-free approach to access difluoroalkylated dioxodibenzothiazepines

Q Xiao, M Lu, Y Deng, JX Jian, QX Tong… - Organic Letters, 2021 - ACS Publications
A simple and mild photoredox catalytic approach to access difluoroalkylated
dioxodibenzothiazepines in high regioselectivity via radical cascade cyclization has been …

Cobalt catalyzed electrochemical [4+ 2] annulation for the synthesis of sultams

Y Cao, Y Yuan, Y Lin, X Jiang, Y Weng, T Wang… - Green …, 2020 - pubs.rsc.org
Cobalt catalyzed electrochemical [4+ 2] annulation of sulfonamides with alkynes is
demonstrated in this work, which provided a practical and environmentally friendly way to …

Electrosynthesis of bridged or fused sulfonamides through complex radical cascade reactions: divergence in medium-sized ring formation

Y Zhang, Z Cai, C Zhao, H Zheng, L Ackermann - Chemical Science, 2023 - pubs.rsc.org
Radical cascade addition is one of the most important and efficient strategies for the
synthesis of valuable heterocycles with structural diversity and complexity. Organic …

Copper-assisted trifluoromethylthiolation/radical cascade cyclization of alkynes to construct SCF 3-containing dioxodibenzothiazepines

X Chen, C Pei, B Liu, J Li, D Zou, Y Wu… - Chemical …, 2022 - pubs.rsc.org
A mild and efficient Cu-assisted trifluoromethylthiolation/radical cascade cyclization of
alkynes with readily available and stable AgSCF3 as the trifluoromethylthiolating reagent …

Photochemical difluoromethylation of alkynes: synthesis of CF 2 H-substituted seven-membered dioxodibenzothiazepines and dibenzazepines

X Chen, Y Geng, B Liu, Y Zhu, D Zou, Y Wu… - Organic Chemistry …, 2023 - pubs.rsc.org
A general and efficient photochemical strategy for difluoromethylation/radical cascade
cyclization of alkynes with sodium difluoromethylsulfinate (NaSO2CF2H) has been …

Sulfoxylate anion radical-induced aryl radical generation and intramolecular arylation for the synthesis of biarylsultams

JK Laha, P Gupta - The Journal of Organic Chemistry, 2022 - ACS Publications
Aryl radical generation from the corresponding aryl halides using an electron donor and
subsequent intramolecular cyclization with arenes could be an important advancement in …

Asymmetric stepwise reductive amination of sulfonamides, sulfamates, and a phosphinamide by nickel catalysis

X Zhao, H Xu, X Huang, JS Zhou - Angewandte Chemie, 2019 - Wiley Online Library
Asymmetric reductive amination of poorly nucleophilic sulfonamides was realized in the
presence of nickel catalysts and titanium alkoxide. A wide range of ketones, including …

Formation of amides, their intramolecular reactions for the synthesis of N-heterocycles, and preparation of a marketed drug, sildenafil: a comprehensive coverage

JK Laha, KV Patel, KSS Tummalapalli… - Chemical …, 2016 - pubs.rsc.org
A unified approach to the tandem preparation of diverse nitrogen heterocycles via
decarboxylative acylation of ortho-substituted amines with α-oxocarboxylic acids and …