It was first reported almost two decades ago that ligands with azo functions are capable of
accepting electron (s) upon coordination to produce azo-anion radical complexes, thereby …

Alcohol is ubiquitous with unparalleled structural diversity and thus has wide applications as
a native functional group in organic synthesis. It is highly prevalent among biomolecules and …

Herein, we described the selective synthesis of both alkylated and alkenylated fluorenes
using a single SNS ligand derived nickel complex. The protocol was employed for a wide …

In the borrowing hydrogen catalysis, hydrogenation of an in situ generated imine or olefinic
bond is a crucial step. There is a growing body of literature in olefinic hydrogenation …

A new and efficient catalytic system for sustainable α-alkylation of carbonyl compounds with
alcohols which serve as alkylating agents via a borrowing hydrogen strategy was presented …

Borrowing hydrogen (BH) reactions by base metals have attracted significant focus with a
perspective in green and sustainable chemistry. In a BH reaction, dehydrogenation of the …

Herein, an efficient and expedient method was developed for α‐alkylation of aromatic
ketones with secondary alcohols to produce β‐disubstituted ketones using phosphine‐free …

A new class of palladium complexes bearing bidentate 2‐hydroxypyridine based ligands
have been prepared and fully characterized. The applications of these new complexes …

The utilization of economical and environmentally benign transition metals in crucial
catalytic processes is pivotal for sustainable advancement in synthetic organic chemistry …

The borrowing hydrogen methodology (BH) has emerged as a powerful tool for the rapid
construction of C–C bonds, offering a greener alternative to traditional multi-step syntheses …