From stable radicals to thermally robust high-spin diradicals and triradicals

C Shu, Z Yang, A Rajca - Chemical Reviews, 2023 - ACS Publications
Stable radicals and thermally robust high-spin di-and triradicals have emerged as important
organic materials due to their promising applications in diverse fields. New fundamental …

Efficient and air-stable n-type doping in organic semiconductors

D Yuan, W Liu, X Zhu - Chemical Society Reviews, 2023 - pubs.rsc.org
Chemical doping of organic semiconductors (OSCs) enables feasible tuning of carrier
concentration, charge mobility, and energy levels, which is critical for the applications of …

Organic radicals with inversion of SOMO and HOMO energies and potential applications in optoelectronics

S Kasemthaveechok, L Abella, J Crassous… - Chemical …, 2022 - pubs.rsc.org
Organic radicals possessing an electronic configuration in which the energy of the singly
occupied molecular orbital (SOMO) is below the highest doubly occupied molecular orbital …

Highly stable neutral corrole radical: amphoteric aromatic–antiaromatic switching and efficient photothermal conversion

H Gao, F Wu, Y Zhao, X Zhi, Y Sun… - Journal of the American …, 2022 - ACS Publications
The preparation of novel stable radical systems that survive and may be manipulated under
harsh conditions is essential for their practical applications, such as energy storage and …

Energy level engineering in gold nanoclusters for exceptionally bright NIR electrochemiluminescence at a low trigger potential

H Peng, M Lai, H Wang, Z Weng, Y Yang… - Analytical …, 2023 - ACS Publications
Electrochemiluminescence (ECL) is a widely used light output mechanism from
electrochemical excitation. Understanding the intrinsic essence for ideal ECL generation …

Achieving Nearly 100% Photoluminescence Quantum Efficiency in Organic Radical Emitters by Fine‐Tuning the Effective Donor‐Acceptor Distance

C Lu, E Cho, K Wan, C Wu, Y Gao… - Advanced Functional …, 2024 - Wiley Online Library
Abstract Donor‐acceptor (D–A•) type luminescent organic radicals have received
widespread attention as efficient doublet emitters. However, their generally low …

Highly Effective Photocatalytic Radical Reactions Triggered by a Photoactive Metal–Organic Framework

D Zhang, XN Zou, XG Wang, J Su… - … Applied Materials & …, 2022 - ACS Publications
On account of their inherent reactive properties, radical reactions play an important role in
organic syntheses. The booming photochemistry provides a feasible approach to trigger the …

A platform for blue-luminescent carbon-centered radicals

X Li, YL Wang, C Chen, YY Ren, YF Han - Nature Communications, 2022 - nature.com
Organic radicals, which have unique doublet spin-configuration, provide an alternative
method to overcome the efficiency limitation of organic light-emitting diodes (OLEDs) based …

Stable radical based conjugated electrolytes as a cathode interlayer for organic solar cells with thickness-insensitive fill factors

J Fang, Z Zhang, Z Zhang, Y Han, D Xia… - Journal of Materials …, 2023 - pubs.rsc.org
In this work, a perylene bisimide (PBI) based electrolyte PDIN-TEMPO pendent with a stable
radical 2, 2, 6, 6-tetramethylpiperidine 1-oxyl (TEMPO) has been synthesized and used as a …

Aromatic Stacking Mediated Spin–Spin Coupling in Cyclophane-Assembled Diradicals

H Han, D Zhang, Z Zhu, R Wei, X Xiao… - Journal of the …, 2021 - ACS Publications
To investigate the capability of π–π stacking motifs to enable spin–spin coupling, we
designed and synthesized three pairs of regio-isomers featuring two radical moieties joined …