From stable radicals to thermally robust high-spin diradicals and triradicals
Stable radicals and thermally robust high-spin di-and triradicals have emerged as important
organic materials due to their promising applications in diverse fields. New fundamental …
organic materials due to their promising applications in diverse fields. New fundamental …
Efficient and air-stable n-type doping in organic semiconductors
Chemical doping of organic semiconductors (OSCs) enables feasible tuning of carrier
concentration, charge mobility, and energy levels, which is critical for the applications of …
concentration, charge mobility, and energy levels, which is critical for the applications of …
Organic radicals with inversion of SOMO and HOMO energies and potential applications in optoelectronics
Organic radicals possessing an electronic configuration in which the energy of the singly
occupied molecular orbital (SOMO) is below the highest doubly occupied molecular orbital …
occupied molecular orbital (SOMO) is below the highest doubly occupied molecular orbital …
Highly stable neutral corrole radical: amphoteric aromatic–antiaromatic switching and efficient photothermal conversion
H Gao, F Wu, Y Zhao, X Zhi, Y Sun… - Journal of the American …, 2022 - ACS Publications
The preparation of novel stable radical systems that survive and may be manipulated under
harsh conditions is essential for their practical applications, such as energy storage and …
harsh conditions is essential for their practical applications, such as energy storage and …
Energy level engineering in gold nanoclusters for exceptionally bright NIR electrochemiluminescence at a low trigger potential
H Peng, M Lai, H Wang, Z Weng, Y Yang… - Analytical …, 2023 - ACS Publications
Electrochemiluminescence (ECL) is a widely used light output mechanism from
electrochemical excitation. Understanding the intrinsic essence for ideal ECL generation …
electrochemical excitation. Understanding the intrinsic essence for ideal ECL generation …
Achieving Nearly 100% Photoluminescence Quantum Efficiency in Organic Radical Emitters by Fine‐Tuning the Effective Donor‐Acceptor Distance
C Lu, E Cho, K Wan, C Wu, Y Gao… - Advanced Functional …, 2024 - Wiley Online Library
Abstract Donor‐acceptor (D–A•) type luminescent organic radicals have received
widespread attention as efficient doublet emitters. However, their generally low …
widespread attention as efficient doublet emitters. However, their generally low …
Highly Effective Photocatalytic Radical Reactions Triggered by a Photoactive Metal–Organic Framework
D Zhang, XN Zou, XG Wang, J Su… - … Applied Materials & …, 2022 - ACS Publications
On account of their inherent reactive properties, radical reactions play an important role in
organic syntheses. The booming photochemistry provides a feasible approach to trigger the …
organic syntheses. The booming photochemistry provides a feasible approach to trigger the …
A platform for blue-luminescent carbon-centered radicals
X Li, YL Wang, C Chen, YY Ren, YF Han - Nature Communications, 2022 - nature.com
Organic radicals, which have unique doublet spin-configuration, provide an alternative
method to overcome the efficiency limitation of organic light-emitting diodes (OLEDs) based …
method to overcome the efficiency limitation of organic light-emitting diodes (OLEDs) based …
Stable radical based conjugated electrolytes as a cathode interlayer for organic solar cells with thickness-insensitive fill factors
In this work, a perylene bisimide (PBI) based electrolyte PDIN-TEMPO pendent with a stable
radical 2, 2, 6, 6-tetramethylpiperidine 1-oxyl (TEMPO) has been synthesized and used as a …
radical 2, 2, 6, 6-tetramethylpiperidine 1-oxyl (TEMPO) has been synthesized and used as a …
Aromatic Stacking Mediated Spin–Spin Coupling in Cyclophane-Assembled Diradicals
To investigate the capability of π–π stacking motifs to enable spin–spin coupling, we
designed and synthesized three pairs of regio-isomers featuring two radical moieties joined …
designed and synthesized three pairs of regio-isomers featuring two radical moieties joined …