Flavinium catalysed photooxidation: detection and characterization of elusive peroxyflavinium intermediates
J Zelenka, R Cibulka, J Roithová - Angewandte Chemie, 2019 - Wiley Online Library
Flavin‐based catalysts are photoactive in the visible range which makes them useful in
biology and chemistry. Herein, we present electrospray‐ionization mass‐spectrometry …
biology and chemistry. Herein, we present electrospray‐ionization mass‐spectrometry …
Visible and ultraviolet spectroscopy of gas phase protein ions
Optical spectroscopy has contributed enormously to our knowledge of the structure and
dynamics of atoms and molecules and is now emerging as a cornerstone of the gas phase …
dynamics of atoms and molecules and is now emerging as a cornerstone of the gas phase …
Two-Dimensional Infrared Spectroscopy of Isolated Molecular Ions
Two-dimensional infrared (2D IR) spectroscopy of mass-selected, cryogenically cooled
molecular ions is presented. Nonlinear response pathways, encoded in the time-domain …
molecular ions is presented. Nonlinear response pathways, encoded in the time-domain …
UV photodissociation of trapped ions following ion mobility separation in a Q-ToF mass spectrometer
An ion mobility mass spectrometer has been modified to allow optical interrogation of ions
with different mass-to-charge (m/z) ratios and/or mobilities (K). An ion gating and trapping …
with different mass-to-charge (m/z) ratios and/or mobilities (K). An ion gating and trapping …
[HTML][HTML] Ultrafast transient vibrational action spectroscopy of cryogenically cooled ions
Ultrafast transient vibrational action spectra of cryogenically cooled Re (CO) 3 (CH 3 CN) 3+
ions are presented. Nonlinear spectra were collected in the time domain by monitoring the …
ions are presented. Nonlinear spectra were collected in the time domain by monitoring the …
Protomer-dependent electronic spectroscopy and photochemistry of the model flavin chromophore alloxazine
E Matthews, R Cercola, CEH Dessent - Molecules, 2018 - mdpi.com
Flavin chromophores play key roles in a wide range of photoactive proteins, but key
questions exist in relation to their fundamental spectroscopic and photochemical properties …
questions exist in relation to their fundamental spectroscopic and photochemical properties …
Observation of near-threshold resonances in the flavin chromophore anions alloxazine and lumichrome
E Matthews, CEH Dessent - The Journal of Physical Chemistry …, 2018 - ACS Publications
Lumichrome (LC) is the chromophore of the flavin family of photoactive biomolecules, where
key biochemical activity involves interplay between redox and photophysical events …
key biochemical activity involves interplay between redox and photophysical events …
Ion mobility action spectroscopy of flavin dianions reveals deprotomer-dependent photochemistry
JN Bull, E Carrascosa, L Giacomozzi… - Physical Chemistry …, 2018 - pubs.rsc.org
The intrinsic optical properties and photochemistry of flavin adenine dinucleotide (FAD)
dianions are investigated using a combination of tandem ion mobility spectrometry and …
dianions are investigated using a combination of tandem ion mobility spectrometry and …
Photodegradation of riboflavin under alkaline conditions: what can gas-phase photolysis tell us about what happens in solution?
NGK Wong, C Rhodes, CEH Dessent - Molecules, 2021 - mdpi.com
The application of electrospray ionisation mass spectrometry (ESI-MS) as a direct method for
detecting reactive intermediates is a technique of developing importance in the routine …
detecting reactive intermediates is a technique of developing importance in the routine …
The membrane-bound C subunit of reductive dehalogenases: topology analysis and reconstitution of the FMN-binding domain of PceC
GF Buttet, MS Willemin, R Hamelin… - Frontiers in …, 2018 - frontiersin.org
Organohalide respiration (OHR) is the energy metabolism of anaerobic bacteria able to use
halogenated organic compounds as terminal electron acceptors. While the terminal …
halogenated organic compounds as terminal electron acceptors. While the terminal …