Recent advances in triplet–triplet annihilation upconversion and singlet fission, towards solar energy applications

AJ Carrod, V Gray, K Börjesson - Energy & Environmental Science, 2022 - pubs.rsc.org
Solar energy is an ample renewable energy resource, with photovoltaic (PV) technology
enabling a direct route from light to electricity. Currently, PVs are limited in photon …

Unconventional singlet fission materials

T Ullrich, D Munz, DM Guldi - Chemical Society Reviews, 2021 - pubs.rsc.org
Singlet fission (SF) is a photophysical downconversion pathway, in which a singlet excitation
transforms into two triplet excited states. As such, it constitutes an exciton multiplication …

Breathing new life into nonalternant hydrocarbon chemistry: Syntheses and properties of polycyclic hydrocarbons containing azulene, pentalene, and heptalene …

A Konishi, M Yasuda - Chemistry Letters, 2021 - academic.oup.com
Abstract Azulene 1, pentalene 2, and heptalene 3 are classical nonalternant hydrocarbons.
Their fascinating π-frameworks, consecutive arrangements of odd-membered carbocycles …

Porphyrinoids, a unique platform for exploring excited-state aromaticity

J Kim, J Oh, A Osuka, D Kim - Chemical Society Reviews, 2022 - pubs.rsc.org
Recently, Baird (anti) aromaticity has been referred to as a description of excited-state (anti)
aromaticity. With the term of Baird's rule, recent studies have intensively verified that the …

Symmetry‐Induced Singlet‐Triplet Inversions in Non‐Alternant Hydrocarbons

J Terence Blaskovits, MH Garner… - Angewandte …, 2023 - Wiley Online Library
Molecules with inversion of the singlet and triplet excited‐state energies are highly
promising for the development of organic light‐emitting diodes (OLEDs). To date …

Molecular engineering of chromophores to enable triplet–triplet annihilation upconversion

KJ Fallon, EM Churchill, SN Sanders… - Journal of the …, 2020 - ACS Publications
Triplet–triplet annihilation upconversion (TTA-UC) is an unconventional photophysical
process that yields high-energy photons from low-energy incident light and offers pathways …

Singlet fission in a pyrrole-fused cross-conjugated skeleton with adaptive aromaticity

L Wang, L Lin, J Yang, Y Wu, H Wang… - Journal of the …, 2020 - ACS Publications
Singlet fission (SF) materials hold the potential to increase the power conversion efficiency
of solar cells by reducing the thermalization of high-energy excited states. The major hurdle …

Controlling the S1 Energy Profile by Tuning Excited-State Aromaticity

R Kotani, L Liu, P Kumar, H Kuramochi… - Journal of the …, 2020 - ACS Publications
The shape of the lowest singlet excited-state (S1) energy profile is of primary importance in
photochemistry and related materials science areas. Here we demonstrate a new approach …

Simple and efficient visualization of aromaticity: bond currents calculated from NICS values

E Paenurk, R Gershoni-Poranne - Physical Chemistry Chemical …, 2022 - pubs.rsc.org
Aromaticity is a fundamental concept in chemistry, underpinning the properties and reactivity
of many organic compounds and materials. The ability to easily and accurately discern …

[HTML][HTML] The application of aromaticity and antiaromaticity to reaction mechanisms

Q Zhu, S Chen, D Chen, L Lin, K Xiao, L Zhao… - Fundamental …, 2023 - Elsevier
Aromaticity, in general, can promote a given reaction by stabilizing a transition state or a
product via a mobility of π electrons in a cyclic structure. Similarly, such a promotion could …