Due to the significance of amide bonds, it is crucial to develop a new catalytic strategy to
produce amides by selective C–N bond cleavage, one of the most potent and rapid …

Amide bond replacement with planar isosteric chalcogen analogues has an important
implication for the properties of the N− C (X) linkage in structural chemistry, biochemistry and …

Highly strained [3.2. 1] bicyclic twisted amide 2 and corresponding amidium 10 were
synthesized for the first time through Ag (I)-mediated halide abstraction. After initial …

A direct cross-coupling between 9 H-fluoren-9-ols and organic azides for the synthesis of
steric hindered 2-amino-2′-ketonyl biaryls was reported. The reaction featured an acid …

By performing appropriate empirical scaling of G4 energy differences, it is possible to
calculate Hammett substituent constants σp, σm, σ−, σ+, and σ+ m with a typical accuracy …