Arynes hold significance for the efficient fusion of (hetero) arenes with diverse substrates,
advancing the construction of complex molecular frameworks. Employing multiple …

Utilization of carbon dioxide as a C1 synthon is highly attractive for the synthesis of valuable
chemicals. However, activation of CO2 is highly challenging, owing to its thermodynamic …

Many recent studies have used KO t Bu in organic reactions that involve single electron
transfer; in the literature, the electron transfer is proposed to occur either directly from the …

Arynes offer immense potential for diversification of benzenoid rings, which occur in
pharmaceuticals, agrochemicals, and liquid crystals. However, accessing these high-energy …

Transition-metal-catalyzed cross-couplings to construct C–C, C–O, and C–N bonds have
revolutionized chemical science. Despite great achievements, these metal catalysts also …

Carbon‐heteroatom bond formation under transition‐metal free conditions provides a
powerful synthetic alternative for the efficient synthesis of valuable molecules. In particular …

Described here is an efficient method to access highly functionalized arynes from
unsymmetrical aryl (mesityl) iodonium tosylate salts. The iodonium salts are prepared in a …

Benzyne has long captivated the attention of chemists and has gained numerous synthetic
achievements. Among typical benzyne generation methods, removal of two vicinal …

Arynes hold immense potential as reactive intermediates in organic synthesis as they
engage in a diverse range of mechanistically distinct chemical reactions. However, the poor …

Aryne chemistry has experienced a remarkable renaissance in recent years, with a
significant increase in the synthetic applications reported for these highly valuable reactive …