Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …

W Jing, H Shen, R Qin, Q Wu, K Liu, N Zheng - Chemical Reviews, 2022 - ACS Publications
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Nanoscale engineering of catalytic materials for sustainable technologies

S Mitchell, R Qin, N Zheng, J Pérez-Ramírez - Nature nanotechnology, 2021 - nature.com
Nanostructured materials of diverse architecture are ubiquitous in industrial catalysis. They
offer exciting prospects to tackle various sustainability challenges faced by society. Since the …

Oxidation‐Reduction Molecular Junction Covalent Organic Frameworks for Full Reaction Photosynthesis of H2O2

JN Chang, Q Li, JW Shi, M Zhang, L Zhang… - Angewandte …, 2023 - Wiley Online Library
The full reaction photosynthesis of H2O2 that can combine water‐oxidation and oxygen‐
reduction without sacrificial agents is highly demanded to maximize the light‐utilization and …

The critical impacts of ligands on heterogeneous nanocatalysis: A review

L Lu, S Zou, B Fang - ACS Catalysis, 2021 - ACS Publications
Ligand utilization is a necessary and powerful technique for the colloidal synthesis of
nanoparticles (NPs) with controllable sizes and regulated morphologies. For catalysis …

High activity and selectivity of single palladium atom for oxygen hydrogenation to H2O2

S Yu, X Cheng, Y Wang, B Xiao, Y Xing, J Ren… - Nature …, 2022 - nature.com
Nanosized palladium (Pd)-based catalysts are widely used in the direct hydrogen peroxide
(H2O2) synthesis from H2 and O2, while its selectivity and yield remain inferior because of …

Metal and metal oxide supported on ordered mesoporous carbon as heterogeneous catalysts

M Gao, L Wang, Y Yang, Y Sun, X Zhao, Y Wan - ACS Catalysis, 2023 - ACS Publications
The evolution of model catalyst systems has experienced single-crystal surfaces of different
transition metals and different crystal faces, two-dimensional systems with nanoparticles …

Strategies to break linear scaling relationships

J Pérez-Ramírez, N López - Nature Catalysis, 2019 - nature.com
The search for new catalytic materials has relied on highly time-and human-resource-
consuming procedures. The appearance of theoretical methods that employ density …

Breaking scaling relationships in alkynol semi-hydrogenation by manipulating interstitial atoms in Pd with d-electron gain

Y Yang, X Zhu, L Wang, J Lang, G Yao, T Qin… - Nature …, 2022 - nature.com
Pd catalysts are widely used in alkynol semi-hydrogenation. However, due to the existence
of scaling relationships of adsorption energies between the key adsorbed species, the …

Direct Synthesis of H2O2 from H2 and O2 on Pd Catalysts: Current Understanding, Outstanding Questions, and Research Needs

DW Flaherty - ACS catalysis, 2018 - ACS Publications
Catalytic reactions that utilize H2O2 as a terminal oxidant possess high selectivities for
industrially relevant oxidations that rival Cl2 mediated chemistry and reactions with organic …

Recent progress in low-dimensional palladium-based nanostructures for electrocatalysis and beyond

B Xu, Y Zhang, L Li, Q Shao, X Huang - Coordination Chemistry Reviews, 2022 - Elsevier
Abstract Low-dimensional palladium (Pd)-based nanomaterials have been widely used as
electrocatalysts, especially in the field of fuel cells, due to their inherent advantages, such as …