Capturing photochemical and photophysical transformations in iron complexes with ultrafast X-ray spectroscopy and scattering
KJ Gaffney - Chemical Science, 2021 - pubs.rsc.org
Light-driven chemical transformations provide a compelling approach to understanding
chemical reactivity with the potential to use this understanding to advance solar energy and …
chemical reactivity with the potential to use this understanding to advance solar energy and …
NHC-based iron sensitizers for DSSCs
Nanostructured dye-sensitized solar cells (DSSCs) are promising photovoltaic devices
because of their low cost and transparency. Ruthenium polypyridine complexes have long …
because of their low cost and transparency. Ruthenium polypyridine complexes have long …
Pyrene-Decoration of a Chromium(0) Tris(diisocyanide) Enhances Excited State Delocalization: A Strategy to Improve the Photoluminescence of 3d6 Metal …
C Wegeberg, D Häussinger… - Journal of the American …, 2021 - ACS Publications
There is a long-standing interest in iron (II) complexes that emit from metal-to-ligand charge
transfer (MLCT) excited states, analogous to ruthenium (II) polypyridines. The 3d6 electrons …
transfer (MLCT) excited states, analogous to ruthenium (II) polypyridines. The 3d6 electrons …
KiMoPack: A python Package for Kinetic Modeling of the Chemical Mechanism
C Müller, T Pascher, A Eriksson… - The Journal of …, 2022 - ACS Publications
Herein, we present KiMoPack, an analysis tool for the ki netic mo deling of transient
spectroscopic data. KiMoPack enables a state-of-the-art analysis routine including data …
spectroscopic data. KiMoPack enables a state-of-the-art analysis routine including data …
Nanosecond Metal-to-Ligand Charge-Transfer State in an Fe (II) Chromophore: Lifetime Enhancement via Nested Potentials
JT Malme, RA Clendening, R Ash, T Curry… - Journal of the …, 2023 - ACS Publications
Examples of Fe complexes with long-lived (≥ 1 ns) charge-transfer states are limited to
pseudo-octahedral geometries with strong σ-donor chelates. Alternative strategies based on …
pseudo-octahedral geometries with strong σ-donor chelates. Alternative strategies based on …
Vibrational wavepacket dynamics in Fe carbene photosensitizer determined with femtosecond X-ray emission and scattering
The non-equilibrium dynamics of electrons and nuclei govern the function of photoactive
materials. Disentangling these dynamics remains a critical goal for understanding …
materials. Disentangling these dynamics remains a critical goal for understanding …
Photostable ruthenium (II) isocyanoborato luminophores and their use in energy transfer and photoredox catalysis
Ruthenium (II) polypyridine complexes are among the most popular sensitizers in
photocatalysis, but they face some severe limitations concerning accessible excited-state …
photocatalysis, but they face some severe limitations concerning accessible excited-state …
Resolving femtosecond solvent reorganization dynamics in an iron complex by nonadiabatic dynamics simulations
DB Zederkof, KB Møller, MM Nielsen… - Journal of the …, 2022 - ACS Publications
The ultrafast dynamical response of solute–solvent interactions plays a key role in transition
metal complexes, where charge transfer states are ubiquitous. Nonetheless, there exist very …
metal complexes, where charge transfer states are ubiquitous. Nonetheless, there exist very …
Multifaceted Deactivation Dynamics of Fe(II) N-Heterocyclic Carbene Photosensitizers
Excited state dynamics of three iron (II) carbene complexes that serve as prototype Earth-
abundant photosensitizers were investigated by ultrafast optical spectroscopy. Significant …
abundant photosensitizers were investigated by ultrafast optical spectroscopy. Significant …
Ultrafast Spectroscopy of Fe (II) Complexes Designed for Solar‐Energy Conversion: Current Status and Open Questions
One major challenge of future sustainable photochemistry is to replace precious and rare
transition metals in applications such as energy conversion or electroluminescence by earth …
transition metals in applications such as energy conversion or electroluminescence by earth …