Organic electrosynthesis is a green strategy for the synthesis of valuable molecules.
Electrochemical reactions using sacrificial metal anodes enable new reactivity to be …

Cross-electrophile coupling (XEC), defined by us as the cross-coupling of two different σ-
electrophiles that is driven by catalyst reduction, has seen rapid progression in recent years …

Owing to the unknown correlation of a metal's ligand and its resulting preferred speciation in
terms of oxidation state, geometry, and nuclearity, a rational design of multinuclear catalysts …

A visible light-induced palladium-catalyzed homologative three-component synthesis of
allylic amines has been developed. This protocol proceeds via a unique mechanism …

Carbonyls and alkenes are versatile functional groups, whose reactivities are cornerstones
of organic synthesis. The selective combination of two carbonyls to form an alkene—a …

The utilization of sulfinyl sulfones in transition-metal-catalyzed synthetic chemistry has rarely
been investigated. Here we report the design and utilization of nickel-catalytic conversion of …

An efficient, electrochemically induced cobalt-catalyzed carbon–germanium bond formation
provides access to a variety of functionalized germane-containing compounds, including …

The reaction of common acyl-metal species (acyl anion) with aldehydes to furnish acyloins
has received much less attention and specifically was restricted to using preformed …

The difunctionalization of unsaturated bonds plays a vital role in the enrichment of molecular
complexity. While various catalytic methods for alkene and alkyne difunctionalization have …

We report a strategic exploitation of trifluoromethyl thianthrenium triflate (TT-CF3+ OTf–) as
both electromediator and CF3 radical precursors for paired electrolysis. Enabled by this …