Emerging Trends in the Chemistry of End-to-End Depolymerization

Z Deng, ER Gillies - JACS Au, 2023 - ACS Publications
Over the past couple of decades, polymers that depolymerize end-to-end upon cleavage of
their backbone or activation of a terminal functional group, sometimes referred to as “self …

The thermodynamics and kinetics of depolymerization: what makes vinyl monomer regeneration feasible?

V Lohmann, GR Jones, NP Truong, A Anastasaki - Chemical Science, 2024 - pubs.rsc.org
Depolymerization is potentially a highly advantageous method of recycling plastic waste
which could move the world closer towards a truly circular polymer economy. However …

Photoassisted radical depolymerization

JB Young, JI Bowman, CB Eades, AJ Wong… - ACS Macro …, 2022 - ACS Publications
Controlled radical polymerization techniques enable the synthesis of polymers with
predetermined molecular weights, narrow molecular weight distributions, and controlled …

Chemical Recycling of Commercial Poly(l-lactic acid) to l-Lactide Using a High-Performance Sn(II)/Alcohol Catalyst System

TM McGuire, A Buchard, C Williams - Journal of the American …, 2023 - ACS Publications
Poly (l-lactic acid)(PLLA) is a leading commercial polymer produced from biomass, showing
useful properties for plastics and fiber applications; after use, it is compostable. One area for …

Depolymerization of polymethacrylates by iron ATRP

MR Martinez, D Schild, F De Luca Bossa… - …, 2022 - ACS Publications
Recycling of polymers has become increasingly relevant with the focus on a circular
economy. Controlled radical polymerizations create an avenue for polymerization and …

Solid-state chemical recycling of polycarbonates to epoxides and carbon dioxide using a heterodinuclear Mg (II) Co (II) catalyst

TM McGuire, AC Deacy, A Buchard… - Journal of the American …, 2022 - ACS Publications
Polymer chemical recycling to monomers (CRM) could help improve polymer sustainability,
but its implementation requires much better understanding of depolymerization catalysis …

A simple, selective, and general catalyst for ring closing depolymerization of polyesters and polycarbonates for chemical recycling

CF Gallin, WW Lee, JA Byers - Angewandte Chemie, 2023 - Wiley Online Library
The ability to efficiently and selectively process mixed polymer waste is important to address
the growing plastic waste problem. Herein, we report that the combination of ZnCl2 and an …

Emerging trends in closed‐loop recycling polymers: Monomer design and catalytic bulk depolymerization

Y Liu, XB Lu - Chemistry–A European Journal, 2023 - Wiley Online Library
Plastics are indispensable materials in modern society; however, their extensive use has
contributed to the depletion of finite natural resources and caused severe environmental …

Designed to degrade: tailoring polyesters for circularity

CV Aarsen, A Liguori, R Mattsson… - Chemical …, 2024 - ACS Publications
A powerful toolbox is needed to turn the linear plastic economy into circular. Development of
materials designed for mechanical recycling, chemical recycling, and/or biodegradation in …

Chemically Recyclable Dithioacetal Polymers via Reversible Entropy‐Driven Ring‐Opening Polymerization

LS Kariyawasam, JF Highmoore… - Angewandte Chemie …, 2023 - Wiley Online Library
In a sustainable circular economy, polymers capable of chemical recycling to monomers are
highly desirable. We report an efficient monomer‐polymer recycling of polydithioacetal …