Oxidative coupling between two hydrocarbons: an update of recent C–H functionalizations
C− C bond formation is a fundamental transformation in organic synthesis. The development
of new synthetic methodology could be considered as a way of pursuing a novel method for …
of new synthetic methodology could be considered as a way of pursuing a novel method for …
Chemicals from alkynes with palladium catalysts
R Chinchilla, C Najera - Chemical reviews, 2014 - ACS Publications
The carbon− carbon triple bond of alkynes is one of the basic functional groups, its reactions
belonging to the foundations of organic chemistry. In the past decades, acetylene chemistry …
belonging to the foundations of organic chemistry. In the past decades, acetylene chemistry …
En route to intermolecular cross-dehydrogenative coupling reactions
Cross-coupling reaction between two C–H bonds has become a fundamental strategy in
synthetic organic chemistry. With its increasing importance in green chemistry, atom …
synthetic organic chemistry. With its increasing importance in green chemistry, atom …
Increasing catalyst efficiency in C− H activation catalysis
T Gensch, MJ James, T Dalton… - Angewandte Chemie …, 2018 - Wiley Online Library
C− H activation reactions with high catalyst turnover numbers are still very rare in the
literature and 10 mol% is a common catalyst loading in this field. We offer a representative …
literature and 10 mol% is a common catalyst loading in this field. We offer a representative …
Rh (III)-and Ir (III)-catalyzed C–H alkynylation of arenes under chelation assistance
An efficient Rh (III)-and Ir (III)-catalyzed, chelation-assisted C–H alkynylation of a broad
scope of (hetero) arenes has been developed using hypervalent iodine-alkyne reagents …
scope of (hetero) arenes has been developed using hypervalent iodine-alkyne reagents …
Cobalt-catalyzed cyclization of aliphatic amides and terminal alkynes with silver-cocatalyst
J Zhang, H Chen, C Lin, Z Liu, C Wang… - Journal of the American …, 2015 - ACS Publications
A new method of cobalt-catalyzed synthesis of pyrrolidinones from aliphatic amides and
terminal alkynes was discovered through a C–H bond functionalization process on …
terminal alkynes was discovered through a C–H bond functionalization process on …
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)H Bonds.
Y Wu, J Wang, F Mao… - Chemistry-An Asian …, 2014 - search.ebscohost.com
The catalytic cross-dehydrogenative coupling (CDC) reaction has received intense attention
in recent years. The attractive feature of this coupling process is the formation of a C C …
in recent years. The attractive feature of this coupling process is the formation of a C C …
Cu (II)-mediated ortho C–H alkynylation of (hetero) arenes with terminal alkynes
Cu (II)-promoted ortho alkynylation of arenes and heteroarenes with terminal alkynes has
been developed to prepare aryl alkynes. A variety of arenes and terminal alkynes bearing …
been developed to prepare aryl alkynes. A variety of arenes and terminal alkynes bearing …
Ligand-Promoted meta-C–H Amination and Alkynylation
Using a modified norbornene (methyl bicyclo [2.2. 1] hept-2-ene-2-carboxylate) as a
transient mediator, meta-C–H amination and meta-C–H alkynylation of aniline and phenol …
transient mediator, meta-C–H amination and meta-C–H alkynylation of aniline and phenol …
Rhodium‐Catalyzed C H Alkynylation of Arenes at Room Temperature
C Feng, TP Loh - Angewandte Chemie, 2014 - Wiley Online Library
The rhodium (III)‐catalyzed ortho C H alkynylation of non‐electronically activated arenes is
disclosed. This process features a straightforward and highly effective protocol for the …
disclosed. This process features a straightforward and highly effective protocol for the …