Oxidative coupling between two hydrocarbons: an update of recent C–H functionalizations

C Liu, J Yuan, M Gao, S Tang, W Li, R Shi… - Chemical …, 2015 - ACS Publications
C− C bond formation is a fundamental transformation in organic synthesis. The development
of new synthetic methodology could be considered as a way of pursuing a novel method for …

Chemicals from alkynes with palladium catalysts

R Chinchilla, C Najera - Chemical reviews, 2014 - ACS Publications
The carbon− carbon triple bond of alkynes is one of the basic functional groups, its reactions
belonging to the foundations of organic chemistry. In the past decades, acetylene chemistry …

En route to intermolecular cross-dehydrogenative coupling reactions

CY Huang, H Kang, J Li, CJ Li - The Journal of Organic Chemistry, 2019 - ACS Publications
Cross-coupling reaction between two C–H bonds has become a fundamental strategy in
synthetic organic chemistry. With its increasing importance in green chemistry, atom …

Increasing catalyst efficiency in C− H activation catalysis

T Gensch, MJ James, T Dalton… - Angewandte Chemie …, 2018 - Wiley Online Library
C− H activation reactions with high catalyst turnover numbers are still very rare in the
literature and 10 mol% is a common catalyst loading in this field. We offer a representative …

Rh (III)-and Ir (III)-catalyzed C–H alkynylation of arenes under chelation assistance

F Xie, Z Qi, S Yu, X Li - Journal of the American Chemical Society, 2014 - ACS Publications
An efficient Rh (III)-and Ir (III)-catalyzed, chelation-assisted C–H alkynylation of a broad
scope of (hetero) arenes has been developed using hypervalent iodine-alkyne reagents …

Cobalt-catalyzed cyclization of aliphatic amides and terminal alkynes with silver-cocatalyst

J Zhang, H Chen, C Lin, Z Liu, C Wang… - Journal of the American …, 2015 - ACS Publications
A new method of cobalt-catalyzed synthesis of pyrrolidinones from aliphatic amides and
terminal alkynes was discovered through a C–H bond functionalization process on …

Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)H Bonds.

Y Wu, J Wang, F Mao… - Chemistry-An Asian …, 2014 - search.ebscohost.com
The catalytic cross-dehydrogenative coupling (CDC) reaction has received intense attention
in recent years. The attractive feature of this coupling process is the formation of a C C …

Cu (II)-mediated ortho C–H alkynylation of (hetero) arenes with terminal alkynes

M Shang, HL Wang, SZ Sun, HX Dai… - Journal of the American …, 2014 - ACS Publications
Cu (II)-promoted ortho alkynylation of arenes and heteroarenes with terminal alkynes has
been developed to prepare aryl alkynes. A variety of arenes and terminal alkynes bearing …

Ligand-Promoted meta-C–H Amination and Alkynylation

P Wang, GC Li, P Jain, ME Farmer, J He… - Journal of the …, 2016 - ACS Publications
Using a modified norbornene (methyl bicyclo [2.2. 1] hept-2-ene-2-carboxylate) as a
transient mediator, meta-C–H amination and meta-C–H alkynylation of aniline and phenol …

Rhodium‐Catalyzed C H Alkynylation of Arenes at Room Temperature

C Feng, TP Loh - Angewandte Chemie, 2014 - Wiley Online Library
The rhodium (III)‐catalyzed ortho C H alkynylation of non‐electronically activated arenes is
disclosed. This process features a straightforward and highly effective protocol for the …