Complexes formed between the heaviest and lightest elements in the periodic table yield the
f-block hydrides, a unique class of compounds with wide-ranging utility and interest, from …

The review presents data on the synthesis, structure, reactivity, and catalytic activity of alkyl
derivatives of rare earth metals in the oxidation state+ 2 (Sm, Eu, Yb) and their analogues …

Chemo‐and regioselectivity are often difficult to control during olefin hydrosilylation
catalyzed by d‐and f‐block metal complexes. The cationic hydride of calcium [CaH]+ …

Redistribution of primary silanes through C–Si and Si–H bond cleavage and reformation
provides a straightforward synthesis of secondary silanes, but the poor selectivity and low …

The bulky monodentate carbazolyl ligand 1, 8-bis (3, 5-ditertbutylphenyl)-3, 6-
ditertbutylcarbazole (dtbpCbz) was employed in the synthesis of monomeric heteroleptic …

Ln (II)(Ln= Yb, Sm) and Ca (II)[NCsp3N] pincer type diarylmethanido complexes [2, 2′-(4-
MeC6H3NMe2) 2CH] 2M (M= Yb (2), Sm (3), Ca (4)) coordinated by a tridentate …

The reactions of amides [tBu2CarbAr2] MN (SiMe3) 2 (THF)(M= Ca (5), Yb (6)) and
[tBu2CarbAr2] MN (SiMe3) 2 (M= Ca (7), Yb (8)) coordinated by a bulky carbazolyl ligand …

Ln( ii ) alkyl complexes: from elusive exotics to catalytic applications - Inorganic Chemistry
Frontiers (RSC Publishing) DOI:10.1039/D1QI00206F Royal Society of Chemistry View PDF …

While transition-metal catalysts have shown the ability to regulate the Markovnikov or anti-
Markovnikov regioselective hydrosilylation of aryl alkenes, the selective control of anti …

The first mononuclear divalent ytterbium hydride complex [(TpAd, iPr) Yb (H)(THF)](TpAd,
iPr= hydrotris (3-adamantyl-5-isopropyl-pyrazolyl) borate)(2) bearing a terminal hydrido …