Conspectus One of the major challenges facing organic synthesis in the 21st century is the
utilization of abundantly available feedstock chemicals for fine chemical synthesis. Regio …

Enantioselective functionalization of C–H bonds offers a powerful solution and
transformative tool for the step-and atom-economical construction of chiral molecular …

The introduction of fluorine‐containing groups into organic molecules can significantly affect
their physical and chemical properties and has long been used as an effective strategy for …

A Co-catalyzed highly regio-and enantioselective reductive coupling of alkynes and
aldehydes has been developed under visible light photoredox dual catalysis. A variety of …

Ketones are among the most widely used intermediates in organic synthesis, and their
synthesis from inexpensive feedstocks could be quite impactful. Regio-and enantioselective …

A cobalt-catalyzed intermolecular three-component coupling of arenes, ethylene, and
alkynes was developed using the well-defined air-stable cationic bis (phosphine) cobalt (I) …

Carbo-and heterocycles are frequently used as crucial scaffolds in natural products, fine
chemicals, and biologically and pharmaceutically active compounds. Transition-metal …

Spirocycles play an important role in drug discovery and development owing to their
inherent three-dimensionality and structural novelty. Despite the recent significant progress …

Despite the current progress achieved in asymmetric hydroacylations, highly
enantioselective catalytic addition of unfunctionalized aldehydes to internal alkenes remains …

This review updates the field of enantioselective domino reactions promoted by chiral
catalysts derived from first row metals, such as zinc, iron, copper, scandium, nickel, cobalt …