The value of organometallic reagents to organic synthesis can hardly be overstated. Every
student of organic chemistry is aware of the virtually unlimited number of compounds that …

Abstract The Pd-catalyzed Suzuki-Miyaura (SM) cross-coupling of organo halides with
organoboron compounds is a widely used tool in organic synthesis for the construction of …

A guide to making optimal use of one of the most important tools available to today's
synthetic organic chemist Compatible with virtually all functional groups without protection …

Despite the wide use of aryl radicals in organic synthesis, current methods to prepare them
from aryl halides, carboxylic acids, boronic acids, and diazonium salts suffer from limitations …

In the presence of catalytic amounts of dichlorobis (triphenylphosphine) palladium or of the x-
allylmolybdenum complex 3, tributyltin hydride adds instantaneouslyat room temperature to …

Solvolysis of (4-rerf-butyl-1-cyclohexenyl) aryliodonium tetrafluoroborates was examined in
alcohol and aqueous solutions at 25—70 C. Phenyliodonio group was found to be a …

We report a convergent and efficient total synthesis of the C-nor D-homo steroidal alkaloid
(+)-heilonine with a hexacyclic ring system, nine stereocenters, and a trans-hydrindane …

The first and asymmetric total synthesis of rubriflordilactone A, a bisnortriterpenoid isolated
from Schisandra rubriflora, has been accomplished in a convergent manner. Two …

Strychnine (1) has played a vital role inthe development of natural products chemistry. First
isolated in 1818 from Strychnos ignatii by Pelletier and Caventou, strychnine was among the …

The first and asymmetric total syntheses of rhodomollins A and B, two rhodomollane type
grayanoids featuring a d-homograyanane carbon skeleton and an oxa-bicyclo [3.2. 1] core …