Iodine‐DMSO catalyzed chemoselective oxidative aromatization and deallylation, nondeallylation of aryl allyl ether of tetrahydro‐β‐carboline

SV Gaikwad, MV Gaikwad… - Journal of Heterocyclic …, 2021 - Wiley Online Library
We have developed a simple method for the chemoselective aromatization of tetrahydro‐β‐
carboline with selective nondeallylation O‐allyl groups in the presence of iodine (100 mol%) …

Emerging Role of Green Oxidant I2/DMSO in Organic Synthesis

PN Reddy, BVS Reddy… - Current Organic Synthesis, 2018 - ingentaconnect.com
Background: I2/DMSO oxidative system catalyzed reactions have received considerable
attention because they represent the advantages of being greener, efficient, atom …

Iodine‐DMSO‐Catalyzed Chemoselective Biomimetic Aromatization of Tetrahydro‐β‐carbolines‐3‐carboxylic Acid: Mechanism Study with DFT‐Calculation

SV Gaikwad, DN Nadimetla, MA Kobaisi… - …, 2019 - Wiley Online Library
A new protocol for the chemoselective aromatization of tetrahydro‐β‐carboline‐3‐carboxylic
acids to direct biomimetic one step synthesis of β‐carboline‐3‐carboxylic acids 2 A‐L using …

[PDF][PDF] A novel and simple strategy for the synthesis of γ-carboline

SV Gaikwada, MV Gaikwadb… - Eurasian Chem …, 2020 - academia.edu
Carbolines are among the most intriguing alkaloids and are classified according to their
position of N in the skeleton as α-, β-, γ-, or δcarbolines [1]. The γ-Carboline alkaloids show …

Reactions of alkyl 4-hydroxybut-2-ynoates with arenes under superelectrophilic activation with triflic acid or HUSY zeolite: Alternative propargylation or allenylation of …

NA Devleshova, SV Lozovskiy, AV Vasilyev - Tetrahedron, 2019 - Elsevier
Reactions of alkyl 4-aryl (or 4, 4-diaryl)-4-hydroxybut-2-ynoates [Ar (H or Ar')(OH) C 4–C 3≡
C 2–CO 2 Alk] with arenes under the action of triflic acid TfOH or HUSY zeolite result in the …

[PDF][PDF] Iodine‐DMSO catalyzed aromatization of polysubstituted cyclohexanone derivatives: An efficient method for the synthesis of polyfunctionized biaryls derivatives

SV Gaikwad, MV Gaikwad… - Journal of Applied …, 2021 - researchgate.net
We have developed a simple method for the regioselective aromatization of Polysubstituted
Cyclohexanone derivatives in the presence of iodine (25 mol%), Pd/C (10 Mol%) in dimethyl …

Chemoselective C-benzoylation of phenols by using AlCl3 under solvent-free conditions

SV Gaikwad, BR Nawghare, PD Lokhande - Bulletin of the Chemical …, 2015 - ajol.info
Substituted phenols were chemo-selectively reacted with benzoylchloride in presence of
aluminum chloride under solvent-free condition to afford the corresponding 2'-hydroxy aryl …