Phosphorus compounds bearing chirality on the P-center are usually qualified as P-
chirogenic or P-stereogenic. This chemical class concerns natural products, agrochemistry …

Since the development of BisP* ligand by Imamoto, P-stereogenic phosphines bearing a
bulky tert-butyl group and a smaller alkyl group have demonstrated extraordinary proficiency …

The construction of phosphorus stereocenters under metal-free conditions remains a
formidable challenge. Herein, we report a mechanistically distinct chiral electrophilic …

Both enantiomers of 2, 3-bis (tert-butylmethylphosphino) quinoxaline (QuinoxP*), 1, 2-bis
(tert-butylmethylphosphino) benzene (BenzP*), and 1, 2-bis (tert-butylmethylphosphino)-4, 5 …

The construction of chiral phosphorus molecules with asymmetric center on the phosphorus
atom has always been considered to be challenging in synthetic chemistry. Such P …

Despite the importance of P-chiral organophosphorus compounds in asymmetric catalysis,
transition metal-catalyzed methods for accessing P-chiral phosphine derivatives are still …

A copper‐catalyzed asymmetric aryl C− P cross‐coupling/cyclization reaction was
successfully developed via dynamic kinetic asymmetric transformation (DYKAT) under mild …

Conspectus Among chiral phosphines, P-stereogenic phosphines provide unparalleled
activity and selectivity and have thus emerged as “state-of-the-art” ligands for asymmetric …

P-stereogenic phosphorus compounds are a ubiquitous and critically important class of
chiral ligands in asymmetric catalysis. Methods for catalytic asymmetric synthesis via a step …

The synthesis of phosphorus molecules presenting a chiral center on the P‐atom, also
known as P‐stereogenic compounds, has long attracted the curiosity of the scientific …