Organotransition metal complexes capable of forming metalloradicals have been an
intriguing subject of study for the past fifty years. Of these, rhodium porphyrin complexes …

Porphyrins and 64Cu have emerged as a novel synergic option for applications in PET
molecular imaging. Both the characteristics and photophysical properties of macrocyclic …

A panel of iridium (III) porphyrin complexes containing axial N-heterocyclic carbene (NHC)
ligand (s) were synthesized and characterized. X-ray crystal structures of the bis-NHC …

A set of triazolylidene (trz) nickel (II) complexes [NiCpX (trz)] was synthesized by a direct
metalation of the corresponding triazolium salt with nickelocene, NiCp2. While at short …

Density functional theory calculations are used to study the energetics of the electrochemical
oxygen evolution reaction (OER) of water and the reverse oxygen reduction reaction (ORR) …

This review highlights the most significant advances that were accomplished in the
chemistry of azolium‐carboxylate betaines within the years 2009–2020. Whenever needed …

The relative lability and transmetallation aptitude of trialkylphosphine and NHC donors,
integrated in semi‐rigid hybrid ligands attached to [Ag4Br4] pseudo‐cubanes, lies in favor of …

Porphyrins and N‐heterocyclic carbenes (NHCs) are both relevant ligands in the fields of
coordination and organometallic chemistry. Despite evident structural differences …

A series of metallophthalocyanine (PcM) complexes with axial N-heterocyclic carbene
ligands (NHC; 1, 3-diisopropylimidazol-2-ylidene (DIP) and 1, 3-dimethylbenzimidazol-2 …

It is well-recognized that N-heterocyclic carbenes (NHCs) ligands have provided a new
dimension to the design of catalysts. Macrocyclic molecules are a class of material chemistry …