Persistent and stable organic radicals: Design, synthesis, and applications

ZX Chen, Y Li, F Huang - Chem, 2021 - cell.com
Open-shell radicals are usually thermodynamically and kinetically unstable due to their
incompletely satisfied valency. However, the rapid development of radical chemistry in the …

Coordination chemistry in the design of heterogeneous photocatalysts

C Gao, J Wang, H Xu, Y Xiong - Chemical Society Reviews, 2017 - pubs.rsc.org
Heterogeneous catalysts have been widely used for photocatalysis, which is a highly
important process for energy conversion, owing to their merits such as easy separation of …

Diradicals

M Abe - Chemical Reviews, 2013 - ACS Publications
Open-shell molecules such as radicals, carbenes, and electronically excited-state molecules
exhibit high energies, and thus, in general, they are quite reactive. 1 The short-lived species …

Pro-aromatic and anti-aromatic π-conjugated molecules: an irresistible wish to be diradicals

Z Zeng, X Shi, C Chi, JTL Navarrete… - Chemical Society …, 2015 - pubs.rsc.org
Aromaticity is an important concept to understand the stability and physical properties of π-
conjugated molecules. Recent studies on pro-aromatic and anti-aromatic molecules …

Low band gap polycyclic hydrocarbons: from closed-shell near infrared dyes and semiconductors to open-shell radicals

Z Sun, Q Ye, C Chi, J Wu - Chemical Society Reviews, 2012 - pubs.rsc.org
Low band gap (Eg< 1.5 eV) polycyclic hydrocarbons have become one of the most important
types of materials for many applications, for example, as semiconductors in organic field …

Influence of azo-based donor modifications on nonlinear optical amplitude of D-π-A based organic chromophores: A DFT/TD-DFT exploration

I Shafiq, I Amanat, M Khalid, MA Asghar, R Baby… - Synthetic Metals, 2023 - Elsevier
Organic heterocyclic fused ring compounds possess remarkable nonlinear optical (NLO)
amplitude, are potentially employed in optical computing and nano-photonics. Herein …

Explorations of the indenofluorenes and expanded quinoidal analogues

CK Frederickson, BD Rose… - Accounts of Chemical …, 2017 - ACS Publications
Conspectus Highly conjugated hydrocarbons have attracted interest for use as active
materials in electronic devices such as organic field effect transistors (OFET) and organic …

Breathing new life into nonalternant hydrocarbon chemistry: Syntheses and properties of polycyclic hydrocarbons containing azulene, pentalene, and heptalene …

A Konishi, M Yasuda - Chemistry Letters, 2021 - academic.oup.com
Abstract Azulene 1, pentalene 2, and heptalene 3 are classical nonalternant hydrocarbons.
Their fascinating π-frameworks, consecutive arrangements of odd-membered carbocycles …

6,12-Diarylindeno[1,2-b]fluorenes: Syntheses, Photophysics, and Ambipolar OFETs

DT Chase, AG Fix, SJ Kang, BD Rose… - Journal of the …, 2012 - ACS Publications
Herein we report the synthesis and characterization of a series of 6, 12-diarylindeno [1, 2-b]
fluorenes (IFs). Functionalization with electron donor and acceptor groups influences the …

First theoretical probe for efficient enhancement of nonlinear optical properties of quinacridone based compounds through various modifications

MU Khan, M Ibrahim, M Khalid, MS Qureshi… - Chemical Physics …, 2019 - Elsevier
In this study, first attempt has been made for theoretical designing of quinacridone (QA) dye
and new QA-based compounds (QA-1 to QA-9) were proposed by installing auxiliary donors …