Persistent and stable organic radicals: Design, synthesis, and applications
Open-shell radicals are usually thermodynamically and kinetically unstable due to their
incompletely satisfied valency. However, the rapid development of radical chemistry in the …
incompletely satisfied valency. However, the rapid development of radical chemistry in the …
Coordination chemistry in the design of heterogeneous photocatalysts
Heterogeneous catalysts have been widely used for photocatalysis, which is a highly
important process for energy conversion, owing to their merits such as easy separation of …
important process for energy conversion, owing to their merits such as easy separation of …
Diradicals
M Abe - Chemical Reviews, 2013 - ACS Publications
Open-shell molecules such as radicals, carbenes, and electronically excited-state molecules
exhibit high energies, and thus, in general, they are quite reactive. 1 The short-lived species …
exhibit high energies, and thus, in general, they are quite reactive. 1 The short-lived species …
Pro-aromatic and anti-aromatic π-conjugated molecules: an irresistible wish to be diradicals
Aromaticity is an important concept to understand the stability and physical properties of π-
conjugated molecules. Recent studies on pro-aromatic and anti-aromatic molecules …
conjugated molecules. Recent studies on pro-aromatic and anti-aromatic molecules …
Low band gap polycyclic hydrocarbons: from closed-shell near infrared dyes and semiconductors to open-shell radicals
Low band gap (Eg< 1.5 eV) polycyclic hydrocarbons have become one of the most important
types of materials for many applications, for example, as semiconductors in organic field …
types of materials for many applications, for example, as semiconductors in organic field …
Influence of azo-based donor modifications on nonlinear optical amplitude of D-π-A based organic chromophores: A DFT/TD-DFT exploration
Organic heterocyclic fused ring compounds possess remarkable nonlinear optical (NLO)
amplitude, are potentially employed in optical computing and nano-photonics. Herein …
amplitude, are potentially employed in optical computing and nano-photonics. Herein …
Explorations of the indenofluorenes and expanded quinoidal analogues
CK Frederickson, BD Rose… - Accounts of Chemical …, 2017 - ACS Publications
Conspectus Highly conjugated hydrocarbons have attracted interest for use as active
materials in electronic devices such as organic field effect transistors (OFET) and organic …
materials in electronic devices such as organic field effect transistors (OFET) and organic …
Breathing new life into nonalternant hydrocarbon chemistry: Syntheses and properties of polycyclic hydrocarbons containing azulene, pentalene, and heptalene …
A Konishi, M Yasuda - Chemistry Letters, 2021 - academic.oup.com
Abstract Azulene 1, pentalene 2, and heptalene 3 are classical nonalternant hydrocarbons.
Their fascinating π-frameworks, consecutive arrangements of odd-membered carbocycles …
Their fascinating π-frameworks, consecutive arrangements of odd-membered carbocycles …
6,12-Diarylindeno[1,2-b]fluorenes: Syntheses, Photophysics, and Ambipolar OFETs
Herein we report the synthesis and characterization of a series of 6, 12-diarylindeno [1, 2-b]
fluorenes (IFs). Functionalization with electron donor and acceptor groups influences the …
fluorenes (IFs). Functionalization with electron donor and acceptor groups influences the …
First theoretical probe for efficient enhancement of nonlinear optical properties of quinacridone based compounds through various modifications
In this study, first attempt has been made for theoretical designing of quinacridone (QA) dye
and new QA-based compounds (QA-1 to QA-9) were proposed by installing auxiliary donors …
and new QA-based compounds (QA-1 to QA-9) were proposed by installing auxiliary donors …