[HTML][HTML] Recent advances in visible light mediated photoinduced aryl radical generation and its application in synthesis
The reactions involving aryl radicals is an efficient strategy for the synthesis of a wide variety
of important molecules. We have highlighted here recent developments on the generation of …
of important molecules. We have highlighted here recent developments on the generation of …
Visible Light Induced Photocatalyst‐Free C− X (X= B, C, O, P, S, Se) Bond Formation of Aryl Halides
Aryl halides are one of the most important chemical feedstocks in pharmaceuticals due to its
easy accessibility, inexpensiveness, and widely utilized as aryl radical precursors in organic …
easy accessibility, inexpensiveness, and widely utilized as aryl radical precursors in organic …
Strain‐Release Driven Epoxidation and Aziridination of Bicyclo [1.1. 0] butanes via Palladium Catalyzed σ‐Bond Nucleopalladation
B Wölfl, N Winter, J Li, A Noble… - Angewandte Chemie …, 2023 - Wiley Online Library
The development of preparative methods for the synthesis of four‐membered carbocycles is
gaining increasing importance due to the widespread utility of cyclic compounds in …
gaining increasing importance due to the widespread utility of cyclic compounds in …
Lewis basic salt-promoted organosilane coupling reactions with aromatic electrophiles
Lewis basic salts promote benzyltrimethylsilane coupling with (hetero) aryl nitriles, sulfones,
and chlorides as a new route to 1, 1-diarylalkanes. This method combines the substrate …
and chlorides as a new route to 1, 1-diarylalkanes. This method combines the substrate …
Catalyst-Free Photoinduced C–C Bond Formations
Use of sustainable energy sources in synthetic organic chemistry has become one of the
most popular research topics due to environmental pollution and global warming. In this …
most popular research topics due to environmental pollution and global warming. In this …
Cascade Synthesis of Phenanthrenes under Photoirradiation
Y Li, DE Wise, JK Mitchell… - The Journal of Organic …, 2022 - ACS Publications
We report a photoinduced phenanthrene synthesis from aryl iodides and styrenes through
an arylation/cyclization cascade. Compared to prior methods, this approach obviates the …
an arylation/cyclization cascade. Compared to prior methods, this approach obviates the …
Electroreductive Nickel-Catalyzed Allylation of Aryl Chlorides
X Fu, T Ran, Y Zhou, J Liu - The Journal of Organic Chemistry, 2023 - ACS Publications
Herein, we report a facile and efficient allylation via electrochemical promoted Ni-catalyzed
reductive carbon–carbon bond formation. Readily available (hetero) aryl chlorides with a …
reductive carbon–carbon bond formation. Readily available (hetero) aryl chlorides with a …
Dirhodium (II)-catalyzed diamination reaction via a free radical pathway
Z Fan, Z Wang, R Shi, Y Wang - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
Unlike C–N bond formation with classical dirhodium (II)-nitrenoids as the key intermediate,
dirhodium (II)-catalyzed 1, 2-and 1, 3-diamination reactions are realized by a free radical …
dirhodium (II)-catalyzed 1, 2-and 1, 3-diamination reactions are realized by a free radical …
Generation and Application of Aryl Radicals Under Photoinduced Conditions
A Das, KR Justin Thomas - Chemistry–A European Journal, 2024 - Wiley Online Library
Photoinduced aryl radical generation is a powerful strategy in organic synthesis that
facilitates the formation of diverse carbon‐carbon and carbon‐heteroatom bonds. The …
facilitates the formation of diverse carbon‐carbon and carbon‐heteroatom bonds. The …
Light-Driven Three-Component Carbonylation of Aryl Halides Using Abundant Metal Carbonyl
Q Mou, T Han, M Liu - Organic Letters, 2024 - ACS Publications
Carbonyl compounds are widely found in various pharmaceutical intermediates and
synthetic precursors. Herein we report a simple light-driven three-component aryl halide …
synthetic precursors. Herein we report a simple light-driven three-component aryl halide …