The reactions involving aryl radicals is an efficient strategy for the synthesis of a wide variety
of important molecules. We have highlighted here recent developments on the generation of …

Aryl halides are one of the most important chemical feedstocks in pharmaceuticals due to its
easy accessibility, inexpensiveness, and widely utilized as aryl radical precursors in organic …

The development of preparative methods for the synthesis of four‐membered carbocycles is
gaining increasing importance due to the widespread utility of cyclic compounds in …

Lewis basic salts promote benzyltrimethylsilane coupling with (hetero) aryl nitriles, sulfones,
and chlorides as a new route to 1, 1-diarylalkanes. This method combines the substrate …

Use of sustainable energy sources in synthetic organic chemistry has become one of the
most popular research topics due to environmental pollution and global warming. In this …

We report a photoinduced phenanthrene synthesis from aryl iodides and styrenes through
an arylation/cyclization cascade. Compared to prior methods, this approach obviates the …

Herein, we report a facile and efficient allylation via electrochemical promoted Ni-catalyzed
reductive carbon–carbon bond formation. Readily available (hetero) aryl chlorides with a …

Unlike C–N bond formation with classical dirhodium (II)-nitrenoids as the key intermediate,
dirhodium (II)-catalyzed 1, 2-and 1, 3-diamination reactions are realized by a free radical …

Photoinduced aryl radical generation is a powerful strategy in organic synthesis that
facilitates the formation of diverse carbon‐carbon and carbon‐heteroatom bonds. The …

Carbonyl compounds are widely found in various pharmaceutical intermediates and
synthetic precursors. Herein we report a simple light-driven three-component aryl halide …