Activation of C− H bonds by metal complexes

AE Shilov, GB Shul'pin - Chemical Reviews, 1997 - ACS Publications
Hydrocarbons, especially saturated hydrocarbons (alkanes), are the main constituents of oil
and natural gas, the feedstocks for chemical industry. Therefore, it is obvious that …

Cyclohexane oxidation continues to be a challenge

U Schuchardt, D Cardoso, R Sercheli, R Pereira… - Applied Catalysis A …, 2001 - Elsevier
Many efforts have been made to develop new catalysts to oxidize cyclohexane under mild
conditions. Herein, we review the most interesting systems for this process with different …

Metal-catalyzed hydrocarbon oxygenations in solutions: The dramatic role of additives: A review

GB Shul'pin - Journal of Molecular Catalysis A: Chemical, 2002 - Elsevier
This review describes examples of remarkable acceleration of metal-catalyzed oxidation
reactions by certain additives. In some cases, reactions proceed 2 or 10 times more rapidly …

New trends in oxidative functionalization of carbon–hydrogen bonds: A review

GB Shul'pin - Catalysts, 2016 - mdpi.com
This review describes new reactions catalyzed by recently discovered types of metal
complexes and catalytic systems (catalyst+ co-catalyst). Works of recent years (mainly 2010 …

Advances in the Chemistry of Oxaziridines

KS Williamson, DJ Michaelis, TP Yoon - Chemical reviews, 2014 - ACS Publications
Oxaziridines constitute a subset of a class of versatile oxidants whose characteristic feature
is the presence of two electronegative heteroatoms within a strained three-membered ring …

[HTML][HTML] Metal-catalysed hydrocarbon oxidations

GB Shul'pin - Comptes Rendus Chimie, 2003 - Elsevier
This brief review describes recent findings by the author and his co-workers in the field of
catalytic systems for the oxidation of saturated and aromatic hydrocarbons with molecular …

C–H functionalization: thoroughly tuning ligands at a metal ion, a chemist can greatly enhance catalyst's activity and selectivity

GB Shul'pin - Dalton Transactions, 2013 - pubs.rsc.org
This brief essay consists of a few “exciting stories” devoted to relations within a metal-
complex catalyst between a metal ion and a coordinated ligand. When, as in the case of a …

Oxidations by the reagent “O 2–H 2 O 2–vanadium derivative–pyrazine-2-carboxylic acid”. Part 12. 1 Main features, kinetics and mechanism of alkane …

GB Shul'pin, YN Kozlov, GV Nizova… - Journal of the …, 2001 - pubs.rsc.org
Various combinations of vanadium derivatives (n-Bu4NVO3 is the best catalyst) with
pyrazine-2-carboxylic acid (PCA) catalyse the oxidation of saturated hydrocarbons, RH, with …

Pyrazinecarboxylic acid and analogs: Highly efficient co-catalysts in the metal-complex-catalyzed oxidation of organic compounds

AM Kirillov, GB Shul'pin - Coordination Chemistry Reviews, 2013 - Elsevier
The development of new metal complex catalysts and efficient protocols for the mild and
selective oxidation of alkanes, arenes, olefins, alcohols, and other organic substrates is a …

Immobilized methyltrioxo rhenium (MTO)/H2O2 systems for the oxidation of lignin and lignin model compounds

C Crestini, MC Caponi, DS Argyropoulos… - Bioorganic & medicinal …, 2006 - Elsevier
A convenient and efficient application of heterogeneous methylrhenium trioxide (MTO)
systems for the selective oxidation of lignin model compounds and lignins is reported …