Atomically dispersed noble metal catalysts have drawn wide attention as candidates to
replace supported metal clusters and metal nanoparticles. Atomic dispersion can offer …

Atom‐precise, ligand‐stabilized metalloid clusters have emerged as outstanding model
systems to study fundamental structure and bonding situations of compositionally related …

Heteronuclear metal complexes comprising main group metals and transition metals have
attracted widespread attention from researchers due to their applications in stoichiometric …

A series of zero-valent palladium complexes featuring diphosphinometal ligands is reported.
The metalloligand in the PMP-type framework (M= LiI, CuI, ZnII) acts as a weak to medium …

Metal-only Lewis pairs (MOLPs) based on zinc electrophiles are particularly interesting due
to their relevance to Negishi cross-coupling reactions. Zinc-based ligands in bimetallic …

Recent advances on low valent main group metal chemistry have shown the excellent
potential of heterobimetallic complexes derived from Al (I) to promote cooperative small …

This work provides a facile access to a series of triangular [Zn2M](M= group 10 and 11
metals) clusters. Treatment of Zn–Zn-bonded compounds [L Zn–Zn L](L= CH3C (2, 6-i …

The reaction of terminal zinc hydrides with palladium (0) species afforded an unprecedented
[η2-Zn2Pd] trimetallic complex through the reductive elimination of H2. In contrast, the …

We report the synthesis and reactivity of heterometallic Mg–Ni complexes with bridging
hydrides. Treatment of magnesium monoalkyl complexes, which are supported by a …

Reduction of atmospheric carbon dioxide, which is one of the main components affecting
global warming, and hydrogen storage as a renewable energy source by effective sorbents …