The principle of vinylogy states that the electronic effects of a functional group in a molecule
are possibly transmitted to a distal position through interposed conjugated multiple bonds …

Seven membered heterocyclic Azepine and its derivatives have great pharmacological and
therapeutic implications. In this review, the literature of the last fifty years has been exploited …

Chiral iminium ions—generated upon condensation of α, β-unsaturated aldehydes and
amine catalysts—are used extensively by chemists to make chiral molecules in …

Here we report an asymmetric formal nucleophilic o-cresolylation reaction with the Morita–
Baylis–Hillman (MBH) carbonates from 2-cyclohexanones and diverse aldehydes under …

An enantioselective redox-relay oxidative Heck arylation of 1, 1-disubstituted alkenes to
construct β-stereocenters was developed using a new pyridyl-oxazoline ligand. Various 1, 2 …

Asymmetric catalysis is a rapidly evolving field in synthetic chemistry. This is due to the
growing needs of stereoselective synthetic routes to access enantiopure natural products …

Modulation of the complex reactivity of cyclohexenylidene malononitriles using diverse β-
aryl-substituted enals and proper organocatalytic modalities resulted in divergent …

A chiral Brønsted acid catalysed phosphine‐mediated deoxygenation protocol is reported.
This metal‐free method provides a precise kinetic resolution platform for azaarylethynyl …

Here we report the synthesis of a library of chiral THIQ-fused spirooxindoles, which combine
two privileged scaffolds in antitumor medicinal chemistry. Some of the library members …

Catalytic addition of chiral enamines to azinium salts is a powerful tool for the synthesis of
enantioenriched heterocycles. An unprecedented asymmetric dearomative addition of …