Polymer brushes: Synthesis, characterization, properties and applications
Polymer brushes are thin polymer films in which the individual polymer chains are tethered
by one chain end to a solid interface. The bulk and solution properties of these highly …
by one chain end to a solid interface. The bulk and solution properties of these highly …
Nitroxide-mediated polymerization
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …
(CLRP) technique that enables the design of well-defined, functional and complex …
Nitroxides: applications in synthesis and in polymer chemistry
L Tebben, A Studer - Angewandte Chemie International Edition, 2011 - Wiley Online Library
This Review describes the application of nitroxides to synthesis and polymer chemistry. The
synthesis and physical properties of nitroxides are discussed first. The largest section …
synthesis and physical properties of nitroxides are discussed first. The largest section …
TEMPO in chemical transformations: from homogeneous to heterogeneous
HA Beejapur, Q Zhang, K Hu, L Zhu, J Wang… - ACS Catalysis, 2019 - ACS Publications
The organic nitroxyl radical, TEMPO (2, 2, 6, 6-tetramethylpiperidine-N-oxyl), finds a variety
of industrial applications for chemical transformations. Because of economic and …
of industrial applications for chemical transformations. Because of economic and …
Nitroxide: Anwendungen in der Synthese und in der Polymerchemie
L Tebben, A Studer - Angewandte Chemie, 2011 - Wiley Online Library
Nitroxide werden in der Synthese und in der Polymerchemie verwendet. In diesem Aufsatz
werden zunächst Methoden zur Herstellung von Nitroxiden und deren physikalische …
werden zunächst Methoden zur Herstellung von Nitroxiden und deren physikalische …
Polymer brushes by nitroxide‐mediated polymerization
MK Brinks, A Studer - Macromolecular rapid communications, 2009 - Wiley Online Library
This review article describes the preparation of polymer brushes by nitroxide‐mediated
radical polymerization using either the 'grafting to'or the 'grafting from'approach. The use of …
radical polymerization using either the 'grafting to'or the 'grafting from'approach. The use of …
Surface modification using TEMPO and its derivatives
E Megiel - Advances in Colloid and Interface Science, 2017 - Elsevier
This article provides an overview of the methods for surface modification based on the use of
stable radicals: 2, 2, 6, 6-tetramethylpiperidine-1-oxyl (TEMPO) and its derivatives. Two …
stable radicals: 2, 2, 6, 6-tetramethylpiperidine-1-oxyl (TEMPO) and its derivatives. Two …
Graphene oxide modification with graft polymers via nitroxide mediated radical polymerization
O García-Valdez, R Ledezma-Rodríguez… - Polymer, 2014 - Elsevier
We demonstrate a method to modify the surface of graphene oxide (GO) by grafting polymer
chains using nitroxide mediated radical polymerization (NMRP). Surface modification by …
chains using nitroxide mediated radical polymerization (NMRP). Surface modification by …
Nitroxide-functionalized graphene oxide from graphite oxide
YI Avila-Vega, CC Leyva-Porras, M Mireles… - Carbon, 2013 - Elsevier
A facile method for preparing functionalized graphene oxide single layers with nitroxide
groups is reported herein. Highly oxidized graphite oxide (GO= 83.1%) was obtained …
groups is reported herein. Highly oxidized graphite oxide (GO= 83.1%) was obtained …
Grafting of Chitosan with Styrene and Maleic Anhydride via Nitroxide‐Mediated Radical Polymerization in Supercritical Carbon Dioxide
O García‐Valdez, DG Ramírez‐Wong… - Macromolecular …, 2013 - Wiley Online Library
A novel synthesis route is used to produce chitosan‐graft‐poly (styrene‐maleic anhydride)‐
OH‐TEMPO (CTS‐g‐PSMA‐T). A three‐step reaction scheme is proposed: 1) bromine 4‐OH …
OH‐TEMPO (CTS‐g‐PSMA‐T). A three‐step reaction scheme is proposed: 1) bromine 4‐OH …