Endohedrally doped cage clusters
J Zhao, Q Du, S Zhou, V Kumar - Chemical Reviews, 2020 - ACS Publications
The discovery of carbon fullerene cages and their solids opened a new avenue to build
materials from stable cage clusters as “artificial atoms” or “superatoms” instead of atoms …
materials from stable cage clusters as “artificial atoms” or “superatoms” instead of atoms …
Super atomic clusters: design rules and potential for building blocks of materials
P Jena, Q Sun - Chemical reviews, 2018 - ACS Publications
Atomic clusters, consisting of a few to a few thousand atoms, have emerged over the past 40
years as the ultimate nanoparticles, whose structure and properties can be controlled one …
years as the ultimate nanoparticles, whose structure and properties can be controlled one …
Discovery of a silicon-based ferrimagnetic wheel structure in V x Si 12−(x= 1–3) clusters: Photoelectron spectroscopy and density functional theory investigation
X Huang, HG Xu, S Lu, Y Su, RB King, J Zhao… - Nanoscale, 2014 - pubs.rsc.org
Our studies show that VSi12− adopts a V-centered hexagonal prism with a singlet spin state.
The addition of the second V atom leads to a capped hexagonal antiprism for V2Si12− in a …
The addition of the second V atom leads to a capped hexagonal antiprism for V2Si12− in a …
Recent advances in structural chemistry of Group 14 Zintl ions
C Liu, ZM Sun - Coordination Chemistry Reviews, 2019 - Elsevier
The solution chemistry of Group 14 Zintl-type clusters is of growing interest as a result of
their potential to be used as molecular building blocks for the construction of nanoscale …
their potential to be used as molecular building blocks for the construction of nanoscale …
Magnetic properties of atomic clusters and endohedral metallofullerenes
Magnetic clusters are aggregates of a few to thousands of atoms or molecules that exhibit
magnetism. Understanding the evolution of magnetism from individual atom to bulk solid is …
magnetism. Understanding the evolution of magnetism from individual atom to bulk solid is …
On the structural landscape in endohedral silicon and germanium clusters, M@ Si 12 and M@ Ge 12
JM Goicoechea, JE McGrady - Dalton Transactions, 2015 - pubs.rsc.org
Amongst the endohedral clusters of the tetrel elements, M@ En, the 12-vertex species are
unique in that three completely different geometries, the icosahedron (Ih,[Ni@ Pb12] 2−), the …
unique in that three completely different geometries, the icosahedron (Ih,[Ni@ Pb12] 2−), the …
Recent progress in theoretical and experimental studies of metal-doped silicon clusters: Trend among elements of periodic table
Metal doped silicon clusters with potential applications in the field of optoelectronics,
magnetic and nanomaterials have been extensively studied during last decade. Here in, a …
magnetic and nanomaterials have been extensively studied during last decade. Here in, a …
Evolution of Vibrational Spectra in the Manganese–Silicon Clusters Mn2Sin, n = 10, 12, and 13, and Cationic [Mn2Si13]+
A comparison of DFT-computed and measured infrared spectra reveals the ground state
structures of a series of gas-phase silicon clusters containing a common Mn2 unit. Mn2Si12 …
structures of a series of gas-phase silicon clusters containing a common Mn2 unit. Mn2Si12 …
Structural Evolution and Electronic Properties of V2Sin–/0 (n = 7–14) Clusters: Anion Photoelectron Spectroscopy and Theoretical Calculations
LJ Zhang, B Yang, DZ Li, L Pei, U Farooq… - Inorganic …, 2023 - ACS Publications
A systematic study of the structures and electronic properties of V2-doped silicon clusters,
V2Si n–/0 (n= 7–14), was carried out by anion photoelectron spectroscopic experiments …
V2Si n–/0 (n= 7–14), was carried out by anion photoelectron spectroscopic experiments …
Structural determination of niobium-doped silicon clusters by far-infrared spectroscopy and theory
X Li, P Claes, M Haertelt, P Lievens… - Physical Chemistry …, 2016 - pubs.rsc.org
In this work, the structures of cationic SinNb+ (n= 4–12) clusters are determined using the
combination of infrared multiple photon dissociation (IR-MPD) and density functional theory …
combination of infrared multiple photon dissociation (IR-MPD) and density functional theory …