Staudinger predicted a correlation between the physical properties of a polymer and its main-
chain stereochemistry as early as 1929. 1 However it was not until 1947 that Schildknecht …

Since its discovery, methylalumoxane (MAO) has become of great importance as a
cocatalyst in homogeneous olefin polymerization. The working principles of single‐site …

Ancillary Ligand Effect on Single-Site Styrene Polymerization: Isospecificity of Group 4 Metal
Bis(phenolate) Catalysts | Journal of the American Chemical Society ACS ACS Publications …

Four crystal types (α, β, γ, δ) and some mesophases/sub-modifications have been identified
and discussed in syndiotactic polystyrene (sPS). The α-and β-forms are the main crystal …

This Review aims at a comprehensive overview on the recent stereospecific control
polymerizations by group 3 metal complexes based catalytic systems in combination with …

Long chain branched isotactic polypropylenes (LCBPP) prepared via the combination of rac-
Me2Si (2-Me-4-Ph-Ind) ZrCl2/MAO catalyst and ap-(3-butenyl) styrene (T-reagent) were …

The subject of metallocenes, their synthesis, structural characterization, and application to
catalysis, has been a very active area of research as evidenced by the sheer volume of …

Copolymerizations of styrene and the polyhedral oligomeric silsesquioxane (POSS)–styryl
macromonomer 1‐(4‐vinylphenyl)‐3, 5, 7, 9, 11, 13, 15‐heptacyclopentylpentacyclo [9.5 …

After the first preparation of syndiotactic polystyrene in 1985, the synthesis of this polymer
has gained much interest in the last decade especially in catalyst and polymerization …

This review covers research in olefin polymerization by metallocene catalysts published in
1996. While metallocenes are generally defined as metal complexes with two …