Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R Jin - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Coinage metal clusters: From superatom chemistry to genetic materials

B Yin, Z Luo - Coordination Chemistry Reviews, 2021 - Elsevier
Building metal materials with well-defined components and the monomer-genetic property is
one of the foremost challenges in chemistry and materials science. In recent years, metal …

Sulfide boosting near-unity photoluminescence quantum yield of silver nanocluster

SS Zhang, S Havenridge, C Zhang… - Journal of the …, 2022 - ACS Publications
Silver nanoclusters have emerged as promising candidates for optoelectronic applications,
but their room-temperature photoluminescence quantum yield (PLQY) is far from ideal to …

An Ultrastable 155‐Nuclei Silver Nanocluster Protected by Thiacalix [4] arene and Cyclohexanethiol for Photothermal Conversion

Z Wang, F Alkan, CM Aikens, M Kurmoo… - Angewandte Chemie …, 2022 - Wiley Online Library
Thiacalix [4] arenes have emerged as a family of macrocyclic ligands to protect metal
nanoparticles, but it remains a great challenge to solve the mystery of their structures at the …

Controlled Formation of Fused Metal Chalcogenide Nanoclusters Using Soft Landing of Gaseous Fragment Ions

H Gholipour-Ranjbar, HY Samayoa-Oviedo, J Laskin - ACS nano, 2023 - ACS Publications
The complete ligation of nanoclusters significantly reduces their chemical reactivity, catalytic
activity, and charge transfer properties. Therefore, in applications, nanoclusters are activated …

Near-infrared II emissive metal clusters: From atom physics to biomedicine

H Ma, J Wang, XD Zhang - Coordination Chemistry Reviews, 2021 - Elsevier
Abstract Near-infrared II (NIR-II) imaging at 1100–1700 nm supports deep tissue
penetration, low auto-fluorescence interruption, and high imaging resolution due to …

Ion mobility mass spectrometry for large Synthetic molecules: Expanding the analytical toolbox

N Geue, REP Winpenny, PE Barran - Journal of the American …, 2024 - ACS Publications
Understanding the composition, structure and stability of larger synthetic molecules is crucial
for their design, yet currently the analytical tools commonly used do not always provide this …

Toward controlling the electronic structures of chemically modified superatoms of gold and silver

T Omoda, S Takano, T Tsukuda - Small, 2021 - Wiley Online Library
Atomically precise gold/silver clusters protected by organic ligands L,[(Au/Ag) xLy] z, have
gained increasing interest as building units of functional materials because of their novel …

Disassembly mechanisms and energetics of polymetallic rings and rotaxanes

N Geue, TS Bennett, AAM Arama… - Journal of the …, 2022 - ACS Publications
Understanding the fundamental reactivity of polymetallic complexes is challenging due to
the complexity of their structures with many possible bond breaking and forming processes …

Precise Implantation of an Archimedean Ag@Cu12 Cuboctahedron into a Platonic Cu4Bis(diphenylphosphino)hexane6 Tetrahedron

BL Han, Z Wang, RK Gupta, L Feng, S Wang… - ACS …, 2021 - ACS Publications
Precision loading of nanoclusters in confined spaces, which has been enthusiastically
pursued in the scientific realm, is still associated with some mysteries of “how”,“when”, and …