Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …

W Jing, H Shen, R Qin, Q Wu, K Liu, N Zheng - Chemical Reviews, 2022 - ACS Publications
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Recent advances in the chemistry and applications of N-heterocyclic carbenes

P Bellotti, M Koy, MN Hopkinson, F Glorius - Nature Reviews Chemistry, 2021 - nature.com
N-Heterocyclic carbenes, despite being isolated and characterized three decades ago, still
capture scientists' interest as versatile, modular and strongly coordinating moieties. In the …

MOF encapsulating N‐heterocyclic carbene‐ligated copper single‐atom site catalyst towards efficient methane electrosynthesis

S Chen, WH Li, W Jiang, J Yang, J Zhu… - Angewandte …, 2022 - Wiley Online Library
The exploitation of highly efficient carbon dioxide reduction (CO2RR) electrocatalyst for
methane (CH4) electrosynthesis has attracted great attention for the intermittent renewable …

Luminescent Complexes of Platinum, Iridium, and Coinage Metals Containing N-Heterocyclic Carbene Ligands: Design, Structural Diversity, and Photophysical …

H Amouri - Chemical Reviews, 2022 - ACS Publications
The employment of N-heterocyclic carbenes (NHCs) to design luminescent metal
compounds has been the focus of recent intense investigations because of the strong σ …

Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R Jin - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Transition metal-based catalysts for the electrochemical CO 2 reduction: from atoms and molecules to nanostructured materials

F Franco, C Rettenmaier, HS Jeon… - Chemical Society …, 2020 - pubs.rsc.org
The electrochemical reduction of carbon dioxide (CO2) powered by renewable energy is an
attractive sustainable approach to mitigate CO2 emissions and to produce fuels or value …

N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces

M Koy, P Bellotti, M Das, F Glorius - Nature Catalysis, 2021 - nature.com
Heterogeneous catalysts represent the backbone of many industrial processes and thus
have a considerable societal impact. The active sites of these heterogeneous catalysts are …

N-Heterocyclic Carbene-Stabilized Hydrido Au24 Nanoclusters: Synthesis, Structure, and Electrocatalytic Reduction of CO2

VK Kulkarni, BN Khiarak, S Takano… - Journal of the …, 2022 - ACS Publications
Atomically precise hydrido gold nanoclusters are extremely rare but interesting due to their
potential applications in catalysis. By optimization of molecular precursors, we have …

A CO2‐Masked Carbene Functionalized Covalent Organic Framework for Highly Efficient Carbon Dioxide Conversion

C He, DH Si, YB Huang, R Cao - … Chemie International Edition, 2022 - Wiley Online Library
Free N‐heterocyclic carbenes (NHCs) are generally prepared by treatment of imidazolium
precursors with strong alkali reagents, which usually produces inactive NHC dimers. This …

N-heterocyclic carbene-stabilized gold nanoclusters with organometallic motifs for promoting catalysis

H Shen, Q Wu, S Malola, YZ Han, Z Xu… - Journal of the …, 2022 - ACS Publications
The complexity of heterogeneous metal catalysts makes it challenging to gain insights into
their catalytic mechanisms. Thus, there exists a huge gap between heterogeneous catalysis …