Catalytic Conversion of Cellulose to 5‐Hydroxymethylfurfural: Advancements in Heterogeneous Catalysts and Cutting‐Edge Hydrolysis Strategies

A Rezayan, Y Zhang, B Li, CC Xu - ChemCatChem, 2023 - Wiley Online Library
The catalytic conversion of lignocellulose‐derived carbohydrates, particularly cellulose, into
5‐hydroxymethylfurfural (HMF), holds significant potential as a crucial step in the …

Improved 5-hydroxymethyl-2-furfurylamine production from D-fructose-derived 5-hydroxymethylfurfural by a robust double mutant Aspergillus terreus ω-transaminase …

R Gao, Q Li, J Di, Q Li, YC He, C Ma - Industrial Crops and Products, 2023 - Elsevier
Hydroxymethyl-2-furfurylamine (HMFA) as a key furan-based chemical is a useful
intermediate, which is commonly used in the synthesis of drugs and can also be utilized as a …

Sulfonic acid functionalized dendrimer-grafted cellulose as a solid acid catalyst for the high-yield and green production of 5-hydroxymethylfurfural

M Niakan, M Masteri-Farahani, S Karimi… - Sustainable Energy & …, 2022 - pubs.rsc.org
An efficient heterogeneous acid catalyst was prepared via the growth of a thiol-
functionalized third-generation dendrimer on the surface of cellulose employing thiol–ene …

Recent advances in processes and technologies for production of 5-hydroxymethylfurfural and 2, 5-furandicarboylic acid from carbohydrates

T Shen, L Hou, J Gosset, H Wang, S Leng… - Chemical Engineering …, 2024 - Elsevier
Sugar platform biorefinery has shown promise for production of value-added chemicals such
as 5-Hydroxymethylfurfural (5-HMF) and 2, 5-furandicarboylic acid (FDCA). FDCA is a …

Roles of ball milling pretreatment and titanyl sulfate in the synthesis of 5-hydroxymethylfurfural from cellulose

Q Hou, C Bai, X Bai, H Qian, Y Nie, T Xia… - ACS Sustainable …, 2022 - ACS Publications
Production of 5-hydroxymethylfurfural (HMF) from cellulose has been expected for a long
time, but most catalytic systems generally give low yield and selectivity due to the difficulty of …

Highly efficient, rapid, and practical conversion of carbohydrate into 5-hydroxymethylfurfural using a continuous-flow reactor with 1-(4-sulfobutyl)-3-methylimidazolium …

TH Nguyen, DA Le Nguyen, DD Le, PC Huynh… - Fuel, 2023 - Elsevier
The application of continuous flow reactors for sustainable chemical research and
production has attracted much attention. 5-Hydroxymethylfurfural (5-HMF) has been …

Hydrogel-based heterogeneous-acid-catalysts for converting carbohydrates into the platform chemical: 5-hydroxymethylfurfural

TN Dharmapriya, SY Wu, KL Chang… - Journal of the Taiwan …, 2023 - Elsevier
Abstract Background 5-hydroxymethylfurfural (5-HMF) is a significant platform chemical with
the potential to be converted into hydrocarbon biofuels. Herein, a facile and reusable …

Conversion of glucose to 5-hydroxymethylfurfural in deep eutectic solvent of choline chloride–chromium chloride

X Guo, H Zhu, Y Si, X Lyu, Y Cheng… - Industrial & …, 2022 - ACS Publications
5-Hydroxymethylfurfural (HMF) is a crucial biobased compound for synthesizing chemicals
and biofuels, but the direct conversion of glucose to HMF suffers low yield and purification …

5-HMF production from industrial grade sugar syrups derived from corn and wood using niobium phosphate catalyst in a biphasic continuous-flow tubular reactor

S Souzanchi, L Nazari, KTV Rao, Z Yuan, Z Tan, CC Xu - Catalysis Today, 2023 - Elsevier
This work demonstrated the promise of using industrial-grade sugar syrups derived from
corn and wood, ie, high fructose corn syrup (HFCS), glucose corn syrup (GCS) and wood …

Catalytic dehydration of glucose to 5-HMF using heterogeneous solid catalysts in a biphasic continuous-flow tubular reactor

S Souzanchi, L Nazari, KTV Rao, Z Yuan, Z Tan… - Journal of Industrial and …, 2021 - Elsevier
This work aimed to produce 5-hydroxymethylfurfural (5-HMF) from glucose in a biphasic
continuous-flow tubular reactor with various heterogeneous solid acid catalysts or combined …