Recent progress on controlled polymerizations for functional metallopolymers

X Liu, F Liu, T Abdiryim, R Jamal - Polymer Reviews, 2024 - Taylor & Francis
Metallopolymers with precise structures and particular properties have emerged as
promising functional materials. The applications of metallopolymers depend on the unique …

Heterometallic macromolecules: Synthesis, properties and multiple nanomaterial applications

F Liu, X Liu, T Abdiryim, H Gu, D Astruc - Coordination Chemistry Reviews, 2024 - Elsevier
Metallomacromolecules allow developing advanced materials with various characteristic
properties including inter alia optoelectronics, conductivity, magnetism, self-healing …

pH-responsive gelation in metallo-supramolecular polymers based on the protic pyridinedicarboxamide ligand

M Ahmadi, F Panahi, N Bahri-Laleh, M Sabzi… - Chemistry of …, 2022 - ACS Publications
Pyridinedicarboxamide (PDCA) ligands have been widely integrated into different polymer
chemistries and provided promising self-healing properties in bulk upon adding specific …

Molecular in situ monitoring of the pH-triggered response in adaptive polymers by two-dimensional Raman micro-correlation-spectroscopy

J Hniopek, J Meurer, S Zechel, M Schmitt… - Chemical …, 2023 - pubs.rsc.org
Stimuli-responsive polymers can switch specific physical properties in response to a change
of the environmental conditions. This behavior offers unique advantages in applications …

Application of orthogonal metal–ligand interactions for the synthesis of interpenetrating metallopolymer networks featuring shape-memory and self-healing abilities

J Meurer, T Bätz, J Hniopek, C Bernt… - Journal of Materials …, 2022 - pubs.rsc.org
This study presents the simplified synthetic procedure of rewritable shape-memory
metallopolymers, additionally featuring self-healing abilities. The formation of different …

Coordination Geometry and Mineralization in Self-Healing Mussel-Inspired Hydrogels

M Ahmadi, G Pareras, MB Yeamin… - Chemistry of …, 2024 - ACS Publications
Mussel-inspired polymeric materials have found a broad range of applications not only in
adhesives, coatings, and tough hydrogels but thanks to self-healing and stimuli …

Effect of Coordination Sacrificial Bond Strength on Toughening Properties of Polyesters

J Chen, S Wang, J Huan, Z Li, X Yang, X Li… - Macromolecules, 2024 - ACS Publications
By the coordination of dangling terpyridine (TPY) ligands with transition metal ions to form
supramolecular cross-linking points as sacrificial bonds (SBs), a double-cross-linked system …

[HTML][HTML] Investigation of selective metal-complexation in terpyridine and phenanthroline based polymeric systems

T Bätz, HH Haeri, S Langstein, S Zechel, MD Hager… - Polymer, 2024 - Elsevier
In the current study, we present the synthesis of a polymeric template featuring two adjoining
ligand moieties (ie terpyridine and phenanthroline), which are capable to selectively bind …

Metallopolymers as Functional Materials for Multiple Applications

F Liu, T Abdiryim, X Liu - Polymer, 2024 - Elsevier
Metallopolymers have emerged as a new type of advanced materials for multiple
applications, involving nanoscience, energy storage and conversion, catalysis, as well as …

Thiol‐ene Reaction as Reversible Covalent Bond for the Design of Shape‐Memory Polymers

F Shohraty, J Hniopek, J Meurer… - Macromolecular …, 2023 - Wiley Online Library
Besides a stable phase, shape‐memory polymers require an additional switchable moiety.
In addition to thermal transitions and supramolecular interactions, these units can also be …