Emerging building blocks for medicinal chemistry: recent synthetic advances

OO Grygorenko, DM Volochnyuk… - European Journal of …, 2021 - Wiley Online Library
Current medicinal chemistry relies heavily on the quality of building blocks, ie reagents used
to introduce chemical diversity into the target molecules. The last decade witnessed an …

Halogenation of organic compounds in ionic liquids

J Pavlinac, M Zupan, KK Laali, S Stavber - Tetrahedron, 2009 - Elsevier
The term ionic liquid (IL) generally refers to salts with a melting temperature below the
boiling point of water. Although considerable interest has been shown in ILs in the last …

On the formation of a third, nanostructured domain in ionic liquids

AB Pereiro, MJ Pastoriza-Gallego… - The Journal of …, 2013 - ACS Publications
The study of solid–fluid transitions in fluorinated ionic liquids using differential scanning
calorimetry, rheology, and molecular modeling techniques is an essential step toward the …

Influence of nanosegregation on the phase behavior of fluorinated ionic liquids

ML Ferreira, MJ Pastoriza-Gallego… - The Journal of …, 2017 - ACS Publications
Fluorinated ionic liquids (FILs) have received increasing attention due to their
physicochemical properties. They allow us to enlarge the tuneability power of traditional …

Gas permeation properties of fluorinated ionic liquids

AB Pereiro, LC Tomé, S Martinho… - Industrial & …, 2013 - ACS Publications
Despite the increasing amount of research in the ionic liquids field, there are still quite
unexplored themes. That is the case of the fluorinated ionic liquids (FILs) family, here …

Influence of nanosegregation on the surface tension of fluorinated ionic liquids

A Luís, K Shimizu, JMM Araújo, PJ Carvalho… - Langmuir, 2016 - ACS Publications
We have investigated, both theoretically and experimentally, the balance between the
presence of alkyl and perfluoroalkyl side chains on the surface organization and surface …

Advances in the Synthesis and Application of Tetrafluoroethylene‐and 1, 1, 2, 2‐Tetrafluoroethyl‐Containing Compounds

J Václavík, I Klimánková, A Budinská… - European Journal of …, 2018 - Wiley Online Library
In this review, we provide a comprehensive and critical perspective on the synthesis and
application of 1, 1, 2, 2‐tetrafluoroethyl‐and tetrafluoroethylene‐containing compounds …

Synthesis of fluoroalkyl sulfides via additive-free hydrothiolation and sequential functionalization reactions

DE Sunagawa, N Ishida, H Iwamoto… - The Journal of …, 2021 - ACS Publications
A modular synthetic method, involving a hydrothiolation, silylation, and fluoroalkylation, for
the construction of highly functionalized fluoroalkyl sulfides has been developed. The use of …

Ionic liquid iodinating reagent for mild and efficient iodination of aromatic and heteroaromatic amines and terminal alkynes

M Nouzarian, R Hosseinzadeh… - Synthetic …, 2013 - Taylor & Francis
Hexamethylene bis (N-methylimidazolium) bis (dichloroiodate)(HMBMIBDCI), an ionic liquid
iodinating reagent, have been prepared and characterized. Its ability to perform iodination …

Electrolyte salt for lithium-based energy stores

GV Röschenthaler, M Winter, S Passerini… - US Patent …, 2017 - Google Patents
The invention relates to lithium 1-trifluoromethoxy-1, 2, 2, 2-tetra-fluoroethanesulphonate,
the use of lithium 1-trifluoromethoxy-1, 2, 2, 2-tetra-fluoroethanesulphonate as electrolyte …