Gold complexes in anticancer therapy: From new design principles to particle‐based delivery systems

G Moreno‐Alcántar, P Picchetti… - Angewandte Chemie …, 2023 - Wiley Online Library
The discovery of the medicinal properties of gold complexes has fuelled the design and
synthesis of new anticancer metallodrugs, which have received special attention due to their …

Optimization of catalysts and conditions in gold (I) catalysis—counterion and additive effects

Z Lu, T Li, SR Mudshinge, B Xu… - Chemical …, 2021 - ACS Publications
Gold catalysis has proven to be an important breakthrough for organic synthesis. The
tunable nature of gold catalysts, the unique properties of gold, and the mild reaction …

Recent advances in gold (III) chemistry: structure, bonding, reactivity, and role in homogeneous catalysis

L Rocchigiani, M Bochmann - Chemical Reviews, 2020 - ACS Publications
Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

A cartography of the van der Waals territories

S Alvarez - Dalton Transactions, 2013 - pubs.rsc.org
The distribution of distances from atoms of a particular element E to a probe atom X (oxygen
in most cases), both bonded and intermolecular non-bonded contacts, has been analyzed …

Reactivity of gold complexes towards elementary organometallic reactions

M Joost, A Amgoune… - Angewandte Chemie …, 2015 - Wiley Online Library
For a while, the reactivity of gold complexes was largely dominated by their Lewis acid
behavior. In contrast to the other transition metals, the elementary steps of organometallic …

Rational development of catalytic Au (I)/Au (III) arylation involving mild oxidative addition of aryl halides

A Zeineddine, L Estévez, S Mallet-Ladeira… - Nature …, 2017 - nature.com
The reluctance of gold to achieve oxidative addition reaction is considered as an intrinsic
limitation for the development of gold-catalyzed cross-coupling reactions with simple and …

Ligand effects in homogeneous Au catalysis

DJ Gorin, BD Sherry, FD Toste - Chemical reviews, 2008 - ACS Publications
Despite the ubiquity of metallic gold (Au) in popular culture, its deployment in homogeneous
catalysis has only recently undergone widespread investigation. In the past decade, and …

Relativistic effects in homogeneous gold catalysis

DJ Gorin, FD Toste - Nature, 2007 - nature.com
Transition-metal catalysts containing gold present new opportunities for chemical synthesis,
and it is therefore not surprising that these complexes are beginning to capture the attention …

Molecular confinement effects by self-assembled coordination cages

H Takezawa, M Fujita - Bulletin of the Chemical Society of …, 2021 - academic.oup.com
When substrates are confined in an isolated cavity, they experience circumstances that are
distinctly different from those in a bulk solution. Molecular self-assembly has widened the …

Theoretical chemistry of gold

P Pyykkö - Angewandte Chemie International Edition, 2004 - Wiley Online Library
Theoretical Chemistry of Gold - Pyykkö - 2004 - Angewandte Chemie International Edition - Wiley
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