Three‐coordinate cationic bismuth compounds [Bi (diaryl)(EPMe3)][SbF6] have been
isolated and fully characterized (diaryl=[(C6H4) 2C2H2] 2−, E= S, Se). They represent rare …

Our understanding on the nature of weak intermolecular metal–metal interactions as well as
of multiple bonding in group 15/16 chemistry, in particular of compounds containing the …

The reactions of the organoantimony (I) compound L14Sb4 (1)(where L1=[o-C6H4 (CH
NC6H3 (i-Pr) 2-2, 6)]) with diphenyldichalcogenides PhEEPh (E= S, Se, or Te) gave …

Abstract The molecular compound [BiDipp2 (SbF6)], containing the bulky, donor‐free
bismuth cation [BiDipp2]+ has been synthesized and fully characterized (Dipp= 2, 6‐iPr2 …

Crystal structures of the heavier main group elements in low oxidation states have been
evaluated for the presence of supramolecular element (lp)⋯ π (arene) interactions that are …

The reactions between the diorganobismuth (III) bromides [RCH2N (CH2C6H4) 2] BiBr [R=
C6H5 (1), C6H5CH2 (2)] and appropriate silver salts resulted in new diorganobismuth (III) …

The present review, describing the modern achievements in the area of synthetic methods,
investigation of specific structural features, and possibilities of practical use of the organic …

Bis [dibenzobismepine], a dibismuthane composed of two bismepine units (R2Bi− BiR2),
was synthesized and fully characterized (R2=(C6H4CH) 2). Reactions of this dibismuthane …

Diethylstibanyl‐and diethylbismuthanyl telluranes Et2MTeEt (M= Sb 1, Bi 2) as well as
tBu3Sb (3) were structurally characterized by single‐crystal X‐ray diffraction. Single crystals …

In this manuscript a curious behavior observed in the solid state of several X-ray structures
retrieved from the Cambridge structural database (CSD) is described and analyzed. These …