The LAM of the rings: Large amplitude motions in aromatic molecules studied by microwave spectroscopy
HVL Nguyen, W Caminati, JU Grabow - Molecules, 2022 - mdpi.com
Large amplitude motions (LAMs) form a fundamental phenomenon that demands the
development of specific theoretical and Hamiltonian models. In recent years, along with the …
development of specific theoretical and Hamiltonian models. In recent years, along with the …
Comprehensive survey of VUV induced dissociative photoionisation of aniline: Role of H migration assisted isomerisation
A complete dissociation progression of aniline under VUV irradiation over the entire relevant
internal energy range and inclusive of all decay channels is presented. The onset energy …
internal energy range and inclusive of all decay channels is presented. The onset energy …
Five-membered ring compounds from the ortho-benzyne + methyl radical reaction under interstellar conditions
J Bouwman, MN McCabe, CN Shingledecker… - Nature …, 2023 - nature.com
Reactive open-shell species, such as radicals and biradicals, are key intermediates in the
formation of (poly) cyclic hydrocarbon species in a variety of interstellar environments …
formation of (poly) cyclic hydrocarbon species in a variety of interstellar environments …
Rotational spectra and semi-experimental structures of furonitrile and its water cluster
Rotational spectroscopy represents an invaluable tool for several applications: from the
identification of new molecules in interstellar objects to the characterization of van der Waals …
identification of new molecules in interstellar objects to the characterization of van der Waals …
Oxygen-bearing organic molecules in comet 67P's dusty coma: First evidence for abundant heterocycles
N Hänni, K Altwegg, D Baklouti, M Combi… - Astronomy & …, 2023 - aanda.org
The puzzling complexity of terrestrial biomolecules is driving the search for complex organic
molecules in the interstellar medium (ISM) and serves as a motivation for many in situ …
molecules in the interstellar medium (ISM) and serves as a motivation for many in situ …
Electronic spectroscopy of monocyclic carbon ring cations for astrochemical consideration
J Rademacher, ES Reedy… - The Journal of Physical …, 2022 - ACS Publications
Gas phase electronic spectra of pure carbon cations generated by laser vaporization of
graphite in a supersonic jet and cooled to below 10 K and tagged with helium atoms in a …
graphite in a supersonic jet and cooled to below 10 K and tagged with helium atoms in a …
Ionic fragmentation products of benzonitrile as important intermediates in the growth of polycyclic aromatic hydrocarbons
In various astronomical environments such as the interstellar medium or (exo) planetary
atmospheres, an interplay of bottom-up growth and top-down destruction processes of …
atmospheres, an interplay of bottom-up growth and top-down destruction processes of …
Chirped-pulse Fourier transform millimeter-wave spectroscopy of furan, isotopologues, and vibrational excited states
Recent astronomical detections of several five-and six-membered carbon rings in the
interstellar medium (ISM) have expanded our understanding of the chemistry operative in …
interstellar medium (ISM) have expanded our understanding of the chemistry operative in …
Methanol in the RNA world: An astrochemical perspective
T Mathew, PM Esteves, GKS Prakash - Frontiers in Astronomy and …, 2022 - frontiersin.org
The role and relevance of methanol in the origin and structure of the RNA world is
discussed. Methanol is a pivotal, renewable, and regenerable source from which almost all …
discussed. Methanol is a pivotal, renewable, and regenerable source from which almost all …
Toward the limits of complexity of interstellar chemistry: Rotational spectroscopy and astronomical search for n-and i-butanal
M Sanz-Novo, A Belloche, VM Rivilla… - Astronomy & …, 2022 - aanda.org
Context. In recent times, large organic molecules of exceptional complexity have been found
in diverse regions of the interstellar medium. Aims. In this context, we aim to provide …
in diverse regions of the interstellar medium. Aims. In this context, we aim to provide …