Introduction to chemical warfare agents, relevant simulants and modern neutralisation methods

B Picard, I Chataigner, J Maddaluno… - Organic & Biomolecular …, 2019 - pubs.rsc.org
Despite international prohibition, some ill-intentioned states and organisations have shown
their will and capacity to run chemical weapon programs, and the number of incidents …

[HTML][HTML] Use of isothermal titration calorimetry to study surfactant aggregation in colloidal systems

W Loh, C Brinatti, KC Tam - Biochimica et Biophysica Acta (BBA)-General …, 2016 - Elsevier
Background Isothermal titration calorimetry (ITC) is a general technique that allows for
precise and highly sensitive measurements. These measurements may provide a complete …

Functionalized polyacrylamide as an acetylcholinesterase-inspired biomimetic device for electrochemical sensing of organophosphorus pesticides

LF Sgobbi, SAS Machado - Biosensors and Bioelectronics, 2018 - Elsevier
A plethora of publications has continuously reported electrochemical biosensors for
detection of pesticides. However, those devices rarely accomplish commercial application …

Organophosphorus chemical security from a peaceful perspective: Sustainable practices in its synthesis, decontamination and detection

VB Silva, YH Santos, R Hellinger, S Mansour… - Green …, 2022 - pubs.rsc.org
Organophosphorus compounds play an important role in the modern chemical industry and
have a broad range of applications as flame retardants, agrochemicals, and chemical …

[HTML][HTML] pKa determination of graphene-like materials: Validating chemical functionalization

ES Orth, JGL Ferreira, JES Fonsaca… - Journal of colloid and …, 2016 - Elsevier
We report a novel pK a determination for different graphene-like samples: graphene oxide
(GO), reduced GO (rGO), graphene nanoribbons (GNR), oxidized GNR (GONR), thiol-and …

Advances in nanoreactor technology using polymeric nanostructures

A Lu, RK O'Reilly - Current opinion in biotechnology, 2013 - Elsevier
Site isolation, compartmentalization and substrate specificity are a few of the characteristics
responsible for the catalytic efficiency demonstrated by enzymes in natural systems. In …

Hydroxamic acid: an underrated moiety? Marrying bioinorganic chemistry and polymer science

J Keth, T Johann, H Frey - Biomacromolecules, 2020 - ACS Publications
Even 150 years after their discovery, hydroxamic acids are mainly known as the starting
material for the Lossen rearrangement in textbooks. However, hydroxamic acids feature a …

From DNA to nerve agents–the biomimetic catalysts for the hydrolysis of phosphate esters

L Jiang, Y Sun, Y Chen, P Nan - ChemistrySelect, 2020 - Wiley Online Library
The phosphate ester bonds are widely present in living organisms and in the environment.
From the nucleic acids to the sparingly dispersed pesticides and chemical warfare residues …

Imidazole-derived graphene nanocatalysts for organophosphate destruction: Powder and thin film heterogeneous reactions

L Hostert, SF Blaskievicz, JES Fonsaca… - Journal of …, 2017 - Elsevier
Promoting efficient organophoshate (OP) destruction has been of increasing interest, mainly
due to their highly toxic nature and broad use as agrochemicals and chemical warfare. It is …

Supramolecular polymer/surfactant complexes as catalysts for phosphate transfer reactions

AP Gerola, EH Wanderlind, YS Gomes, LA Giusti… - ACS …, 2017 - ACS Publications
Designing artificial enzymes with tailored molecular interactions between the substrate and
active site is of major intellectual and practical significance. We report the improved catalytic …